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Redox Reaction and Electrode Potential

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Estimated time: 6 minutes
Maharashtra State Board: Class 12

Key Points: Redox Reaction and Electrode Potential

Electrochemical Cell:

An electrochemical cell converts chemical energy (from a redox reaction) into electrical energy. The classic example is the Daniell cell (Zn–Cu cell).

Key terms:

Term Description
Flow of electrons Electrons travel through the external circuit from anode (−) to cathode (+)
Flow of current Conventional current flows from cathode to anode (opposite to electron flow)
Electrode potential The electrical potential developed at an electrode when it is in contact with its ion solution
Electrode reaction The half-reaction (oxidation or reduction) that takes place at an electrode
Redox couple The two chemical species (oxidised and reduced forms) linked by electron transfer, forming a half-cell
  • A large negative value of E° means the redox couple is a strong reducing agent (readily loses electrons)
  • Fluorine has the highest positive E° value — it has the greatest tendency to gain electrons (strongest oxidising agent)
  • A strong oxidising agent and a strong reducing agent should never be stored together — they can react violently
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