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Draw the M.O diagram for oxygen molecule calculate its bond order and show that O2 is paramagnetic.
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Draw MO diagram of CO and calculate its bond order.
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What do you understand by Linear combination of atomic orbitals in MO theory?
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Discuss the formation of N2 molecule using MO Theory.
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Hydrogen gas is diatomic whereas inert gases are monoatomic – Explain on the basis of MO theory.
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Of the ions Ti4+, Co2+ and Cr3+, ____________.
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The correct thermodynamic conditions for the spontaneous reaction at all temperature is
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∆S is expected to be maximum for the reaction
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The values of ∆H and ∆S for a reaction are respectively 30 kJ mol–1 and 100 JK–1 mol–1. Then the temperature above which the reaction will become spontaneous is
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What is the usual definition of entropy?
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What is the unit of entropy?
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The Van't Hoff factor (i) for a dilute aqueous solution of the strong elecrolyte barium hydroxide is (NEET) ______.
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The freezing point depression constant for water is 1.86° K Kg mol-1. If 5 g Na2SO4 is dissolved in 45 g water, the depression in freezing point is 3.64°C. The Vant Hoff factor for Na2SO4 is ______.
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Identify the state and path functions out of the following:
- Enthalpy
- Entropy
- Heat
- Temperature
- Work
- Free energy
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Phenol dimerizes in benzene having van’t Hoff factor 0.54. What is the degree of association?
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State the various statements of the second law of thermodynamics.
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What are spontaneous reactions?
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Calculate the entropy change in the system, and surroundings, and the total entropy change in the universe during a process in which 245 J of heat flows out of the system at 77°C to the surrounding at 33°C.
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1 mole of an ideal gas, maintained at 4.1 atm and at a certain temperature, absorbs heat 3710 J and expands to 2 litres. Calculate the entropy change in the expansion process.
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30.4 kJ is required to melt one mole of sodium chloride. The entropy change during melting is 28.4 JK−1 mol−1. Calculate the melting point of sodium chloride.
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