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The substance ‘X’, when dissolved in solvent water gave molar mass corresponding to the molecular formula ‘X3’. The van’t Hoff factor (i) is _______.
(A) 3
(B) 0.33
(C) 1.3
(D) 1
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What is natural rubber?
(A) Cis-1,4-polyisoprene
(B) Neoprene
(C) Trans-1,4-polyisoprene
(D) Butyl rubber
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What is the value of for the following reaction at 298 K -
6CO2+ 6H20(l) → C6H1206(s) + 602(g),
Given that: ΔG° = 2879 kj mol-1, AS = -210 JK-1 mol-1.
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State and explain Hess’s law of constant heat summation.
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With the help of the equation ΔG° = - nFEocell. Explain that cell potential is an intensive property.
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Define van’t Hoff factor.
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A unit cell of iron crystal has edge length 288 pm and density 7.86 g.cm-3. Find the number of atoms per unit cell and type of the crystal lattice.
Given : Molar mass of iron = 56 g.mol-1; Avogadro's number NA = 6.022 x 1023.
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Mohr’s Salt is -
(a) Ferrous ammonium sulphate
(b) Ferrous sulphate
(c) Ammonium sulphate
(d) Ferric sulphate
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How many atoms constitute one unit cell of a face-centered cubic crystal?
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Gold occurs as face centred cube and has a density of 19.30 kg dm-3. Calculate atomic radius of gold. (Molar mass of Au = 197)
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Face centred cubic crystal lattice of copper has density of 8.966 g.cm-3. Calculate the volume of the unit cell. Given molar mass of copper is 63.5 g mol-1 and Avogadro number NA is 6.022 x 1023 mol-1
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Write a note on the self oxidation-reduction reaction of an aldehyde with a suitable example.
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Write names and chemical formulae of monomers used in preparing Buna-S.
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Mention 'two' functions of lipids
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An element crystallises in a b.c.c lattice with cell edge of 500 pm. The density of the element is 7.5g cm-3. How many atoms are present in 300 g of the element?
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Following reactions occur at cathode during the electrolysis of aqueous silver chloride solution :
`Ag^+(aq)+e^(-)rarrAg(s)" "" "" "E^@=+0.80V`
`H^+(aq)+e^(-)rarr1/2H_2(g)" "" "" " E^@=0.00V`
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
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3.9 g of benzoic acid dissolved in 49 g of benzene shows a depression in freezing point of 1.62 K. Calculate the van't Hoff factor and predict the nature of solute (associated or dissociated).
(Given : Molar mass of benzoic acid = 122 g mol−1, Kf for benzene = 4.9 K kg mol−1)
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An element with molar mass 27 g mol−1 forms a cubic unit cell with edge length 4.05 ✕ 10−8 cm. If its density is 2.7 g cm−3, what is the nature of the cubic unit cell?
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