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In a room containing air, heat can go from one place to another
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In an isothermal process on an ideal gas, the pressure increases by 0.5%. The volume decreases by about
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Two samples A and B are initially kept in the same state. Sample A is expanded through an adiabatic process and the sample B through an isothermal process. The final volumes of the samples are the same. The final pressures in A and B are pA and pBrespectively.
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Let ∆Wa and ∆Wb be the work done by the systems A and B, respectively, in the previous question.
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Consider the processes A and B shown in the figure. It is possible that

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Three identical adiabatic containers A, B and C contain helium, neon and oxygen, respectively, at equal pressure. The gases are pushed to half their original volumes.
(a) The final temperatures in the three containers will be the same.
(b) The final pressures in the three containers will be the same.
(c) The pressures of helium and neon will be the same but that of oxygen will be different.
(d) The temperatures of helium and neon will be the same but that of oxygen will be different.
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5 g of a gas is contained in a rigid container and is heated from 15°C to 25°C. Specific heat capacity of the gas at constant volume is 0.172 cal g−1 °C−1 and the mechanical equivalent of heat is 4.2 J cal−1. Calculate the change in the internal energy of the gas
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A sample of air weighing 1.18 g occupies 1.0 × 103 cm3 when kept at 300 K and 1.0 × 105 Pa. When 2.0 cal of heat is added to it at constant volume, its temperature increases by 1°C. Calculate the amount of heat needed to increase the temperature of air by 1°C at constant pressure if the mechanical equivalent of heat is 4.2 × 107 erg cal−1. Assume that air behaves as an ideal gas.
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An ideal gas expands from 100 cm3 to 200 cm3 at a constant pressure of 2.0 × 105 Pa when 50 J of heat is supplied to it. Calculate (a) the change in internal energy of the gas (b) the number of moles in the gas if the initial temperature is 300 K (c) the molar heat capacity Cp at constant pressure and (d) the molar heat capacity Cv at constant volume.
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A mixture contains 1 mole of helium (Cp = 2.5 R, Cv = 1.5 R) and 1 mole of hydrogen (Cp= 3.5 R, Cv = 2.5 R). Calculate the values of Cp, Cv and γ for the mixture.
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In Joly's differential steam calorimeter, 3 g of an ideal gas is contained in a rigid closed sphere at 20°C. The sphere is heated by steam at 100°C and it is found that an extra 0.095 g of steam has condensed into water as the temperature of the gas becomes constant. Calculate the specific heat capacity of the gas in J g−1 K−1. The latent heat of vaporisation of water = 540 cal g−1
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One end of a steel rod (K = 46 J s−1 m−1°C−1) of length 1.0 m is kept in ice at 0°C and the other end is kept in boiling water at 100°C. The area of cross section of the rod is 0.04 cm2. Assuming no heat loss to the atmosphere, find the mass of the ice melting per second. Latent heat of fusion of ice = 3.36 × 105 J kg−1.
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Air (γ = 1.4) is pumped at 2 atm pressure in a motor tyre at 20°C. If the tyre suddenly bursts, what would be the temperature of the air coming out of the tyre? Neglect any mixing with the atmospheric air.
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A steel frame (K = 45 W m−1°C−1) of total length 60 cm and cross sectional area 0.20 cm2, forms three sides of a square. The free ends are maintained at 20°C and 40°C. Find the rate of heat flow through a cross section of the frame.
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The figure shows two vessels with adiabatic walls, one containing 0.1 g of helium (γ = 1.67, M = 4 g mol−1) and the other containing some amount of hydrogen (γ = 1.4, M = 2 g mol−1). Initially, the temperatures of the two gases are equal. The gases are electrically heated for some time during which equal amounts of heat are given to the two gases. It is found that the temperatures rise through the same amount in the two vessels. Calculate the mass of hydrogen.

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A cubical box of volume 216 cm3 is made up of 0.1 cm thick wood. The inside is heated electrically by a 100 W heater. It is found that the temperature difference between the inside and the outside surface is 5°C in steady state. Assuming that the entire electrical energy spent appears as heat, find the thermal conductivity of the material of the box.
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Following Figure shows water in a container having 2.0 mm thick walls made of a material of thermal conductivity 0.50 W m−1°C−1. The container is kept in a melting-ice bath at 0°C. The total surface area in contact with water is 0.05 m2. A wheel is clamped inside the water and is coupled to a block of mass M as shown in the figure. As the block goes down, the wheel rotates. It is found that after some time a steady state is reached in which the block goes down with a constant speed of 10 cm s−1 and the temperature of the water remains constant at 1.0°C. Find the mass M of the block. Assume that the heat flows out of the water only through the walls in contact. Take g = 10 m s−2.

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The speed of sound in hydrogen at 0°C is 1280 m s−1. The density of hydrogen at STP is 0.089 kg m−3. Calculate the molar heat capacities Cp and Cv of hydrogen.
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4.0 g of helium occupies 22400 cm3 at STP. The specific heat capacity of helium at constant pressure is 5.0 cal K−1 mol−1. Calculate the speed of sound in helium at STP.
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Standing waves of frequency 5.0 kHz are produced in a tube filled with oxygen at 300 K. The separation between the consecutive nodes is 3.3 cm. Calculate the specific heat capacities Cp and Cv of the gas.
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