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Science (English Medium) Class 12 - CBSE Question Bank Solutions for Chemistry

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Chemistry
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The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element is a strong oxidising agent in +3 oxidation state and why?

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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Why do the transition elements have higher enthalpies of atomisation?

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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In 3d series (Sc to Zn), which element has the lowest enthalpy of atomisation and why?

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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Give reasons for the following observations:

Physisorption decreases with increase in temperature.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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How would you account for the following: Transition metals form complex compounds.

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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Write the names and structures of the monomers of the following polymers: Buna-N

[15] Polymers
Chapter: [15] Polymers
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Differentiate between adsorbtion and absorption.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Give reasons:

Transition metals show variable oxidation states.

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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Write the name of two monosaccharides obtained on hydrolysis of lactose sugar.

[10] Biomolecules
Chapter: [10] Biomolecules
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What is the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3rd of tetrahedral voids?

[1] Solid State
Chapter: [1] Solid State
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What are the transition elements? Write two characteristics of the transition elements.

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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How would you account for the following : Transition metals form coloured compounds

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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Write the product obtained when D-glucose reacts with H2N − OH.

[10] Biomolecules
Chapter: [10] Biomolecules
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Define the following term: Primitive unit cells

[1] Solid State
Chapter: [1] Solid State
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Account for the following:

Cu+ ion is unstable in aqueous solution.

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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`E_((M^(2+)/M)`

Cr Mn Fe Co Ni Cu
-0.91 -1.18 -0.44 -0.28 -0.25 -0.34

From the given data of E0 values, answer the following questions :

(1) Why is `E_(((Cu^(2+))/(Cu)))` value exceptionally positive

(2) Why is `E_(((Mn^(2+))/(Mn)))` value is highly negative as compared to other elements

(3) Which is the stronger reducing agents Cr2+ or Fe2+ ? Give Reason.

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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What is the effect of temperature on chemisorption ?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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How will you distinguish between the following pair of terms?

Crystal lattice and unit cell

[1] Solid State
Chapter: [1] Solid State
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Account for the following:

Zn is not considered as a transition element.

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
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Account for the following:

E° value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+.

[4] The d-block and f-block Elements
Chapter: [4] The d-block and f-block Elements
Concept: undefined >> undefined
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