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The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co
Answer the following: Which element is a strong oxidising agent in +3 oxidation state and why?
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Why do the transition elements have higher enthalpies of atomisation?
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In 3d series (Sc to Zn), which element has the lowest enthalpy of atomisation and why?
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Give reasons for the following observations:
Physisorption decreases with increase in temperature.
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How would you account for the following: Transition metals form complex compounds.
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Write the names and structures of the monomers of the following polymers: Buna-N
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Differentiate between adsorbtion and absorption.
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Give reasons:
Transition metals show variable oxidation states.
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Write the name of two monosaccharides obtained on hydrolysis of lactose sugar.
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What is the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3rd of tetrahedral voids?
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What are the transition elements? Write two characteristics of the transition elements.
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How would you account for the following : Transition metals form coloured compounds
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Write the product obtained when D-glucose reacts with H2N − OH.
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Define the following term: Primitive unit cells
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Account for the following:
Cu+ ion is unstable in aqueous solution.
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|
`E_((M^(2+)/M)` |
Cr | Mn | Fe | Co | Ni | Cu |
| -0.91 | -1.18 | -0.44 | -0.28 | -0.25 | -0.34 |
From the given data of E0 values, answer the following questions :
(1) Why is `E_(((Cu^(2+))/(Cu)))` value exceptionally positive
(2) Why is `E_(((Mn^(2+))/(Mn)))` value is highly negative as compared to other elements
(3) Which is the stronger reducing agents Cr2+ or Fe2+ ? Give Reason.
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What is the effect of temperature on chemisorption ?
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How will you distinguish between the following pair of terms?
Crystal lattice and unit cell
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Account for the following:
Zn is not considered as a transition element.
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Account for the following:
E° value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+.
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