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An electron is in one of the 3d orbitals. Give the possible values of n, l and ml for this electron.
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The unpaired electrons in Al and Si are present in 3p orbital. Which electrons will experience more effective nuclear charge from the nucleus?
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What is meant by hybridisation of atomic orbitals?
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Describe the shapes of sp, sp2,sp3 hybrid orbitals.
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Describe the change in hybridisation (if any) of the Al atom in the following reaction.
\[\ce{AlCl_3 + Cl- -> AlCl_4-}\]
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Is there any change in the hybridisation of B and N atoms as a result of the following reaction?
\[\ce{BF3 + NH3 → F3B.NH3}\]
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Considering x-axis as the internuclear axis which out of the following will not form a sigma bond and why?
- 1s and 1s
- 1s and 2px
- 2py and 2py
- 1s and 2s.
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Which hybrid orbitals are used by carbon atoms in the following molecules?
CH3–CH3
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For the reaction at 298 K,
\[\ce{2A + B → C}\]
ΔH = 400 kJ mol-1 and ΔS = 0.2 kJ K-1 mol-1
At what temperature will the reaction become spontaneous considering ΔH and ΔS to be constant over the temperature range?
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For the reaction
\[\ce{2A_{(g)} + B_{(g)} → 2D_{(g)}}\]
ΔUθ = –10.5 kJ and ΔSθ= –44.1 JK–1.
Calculate ΔGθ for the reaction, and predict whether the reaction may occur spontaneously.
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Why is benzene extra ordinarily stable though it contains three double bonds?
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Write down the products of ozonolysis of 1, 2-dimethylbenzene (o-xylene). How does the result support Kekulé structure for benzene?
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Give a brief description of the principle of the following technique taking an example.
Distillation
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What is the difference between distillation, distillation under reduced pressure and steam distillation ?
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What will be the conjugate bases for the following Bronsted acids:
HF, H2SO4 and \[\ce{HCO^-_3}\]?
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Which hybrid orbitals are used by carbon atoms in the following molecules?
CH3–CH=CH2
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Which hybrid orbitals are used by carbon atoms in the following molecules?
CH3-CH2-OH
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Which hybrid orbitals are used by carbon atoms in the following molecules?
CH3-CHO
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Which hybrid orbitals are used by carbon atoms in the following molecules?
CH3COOH
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What will be the molarity of a solution, which contains 5.85 g of NaCl(s) per 500 mL?
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