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Karnataka Board PUCPUC Science Class 11

Considering x-axis as the internuclear axis which out of the following will not form a sigma bond and why? (a) 1s and 1s (b) 1s and 2px (c) 2py and 2py (d) 1s and 2s. - Chemistry

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Question

Considering x-axis as the internuclear axis which out of the following will not form a sigma bond and why?

  1. 1s and 1s
  2. 1s and 2px
  3. 2py and 2py
  4. 1s and 2s.
Very Short Answer
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Solution

2py and 2py orbitals will not a form a sigma bond. Taking x-axis as the internuclear axis, 2py and 2py orbitals will undergo lateral overlapping, thereby forming a pi (π) bond.

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