Revision: Atomic Structure Science SSLC (English Medium) Class 9 Tamil Nadu Board of Secondary Education

Mass number— Mass number is the sum of the number of protons and neutrons present in the nucleus of an atom. It is denoted by A.

An atom which becomes charged by losing or gaining electrons is called an ion.

Atom: An atom is the smallest indivisible unit of an
OR
Atom is the smallest unit of matter.

Molecule : Molecule is the smallest unit of a compound (or an element) which always has an independent existance.

Covalent bond— When atoms of different non-metals neither donate nor accept electrons and hence no ions are formed, such a bond is called covalent bond.

Metal:  A chemical element that is an effective conductor of electricity and heat can be defined as a metal.

Ex.: Copper, Iron, Silver, etc.

Metalloid: Metalloid is a chemical element that exhibits some properties of metals and some of non-metals. Metalloids are generally semi-conductors.

Ex.: Silicon. Arsenic, Antimony and Boron.

An atom is the smallest particle of a chemical element that retains its chemical properties.

Chemical bond— A chemical bond is the binding force between two or more atoms of a molecule.

Element: It is a substance that cannot be broken down into simpler substance by chemical means

Ex.: Oxygen, Hydrogen, Gold & Helium.

An atom is the smallest particle of an element which retains its chemical identity in all physical and chemical changes.

Radicals : A radical is an atom of an element or a group of atoms of different elements that behaves as a single unit with a positive or negative charge on it.

An Atom: Smallest particle of an element that can exist and have properties of an element.

Relative atomic mass— Relative atomic mass is the mass of an atom of an element as a multiple of the standard atomic mass unit.

The relative atomic mass of an element is the ratio between the average mass of its isotopes to 1/12th part of the mass of a carbon – 12 atoms. It is denoted as A_r.

Relative atomic mass = `" Average mass of the isotopes of the element"/(1"/"12^{"th"}" of the mass of one Carbon- 12 atom")`

Compound: A compound is a pure substance that is formed when the atoms of two or more elements combine chemically in definite proportions.

Ex: H20, NaCl.

Non-Metal: Non-metal is an element that doesn’t have the characteristics of metal including, (i.e.) ability to conduct heat or electricity luster or flexibility.

Ex. Carbon Iodine, Sulphur.

Atomic number refers to the number of protons present in an atom. It is denoted by Z. Example: An atom of oxygen contains 8 proton Therefore its atomic number is 8.

Mass number refers to the sum of the number of protons and neutrons present in the nucleus of an atom and denoted by A Mass number = Number of protons + Number of neutrons.

The outermost shell of an atom is known as its valence shell.

The protons and neutrons collectively are known as nucleons.

The atomic number of an atom is equal to the number of protons in its nucleus (which is same as the number of electrons in a neutral atom).

The number of protons in the nucleus is known as the atomic number of the element and is denoted by Z.

The number of protons in the nucleus of an atom, which is characteristic of a chemical element and determines its place in the periodic table. Atomic number is also equal to the number of electrons in an atom.

The total number of neutrons and protons in the nucleus is called the mass number of the element and is denoted by A.

The mass number of an atom is equal to the total number of nucleons (i.e., the sum of the number of protons and the number of neutrons) in its nucleus.

Relative atomic mass is defined as the ratio of the average atomic mass to the unified atomic mass unit.

Relative atomic mass (A_r) = `"Average mass of the atom"/"Unified atomic mass"`

The mass of a single atom of an element is called the atomic mass.

When the properties of elements in a period or a group of the modern periodic table are compared, certain regularity is observed in their variations. It is called the periodic trends in the modern periodic table.

The valency of an element is determined by the number of electrons present in the outermost shell of its atoms, that is, the valence electrons.

The atoms of the same element, having same atomic number Z, but different mass number A, are called isotopes.

OR

Atoms having the same atomic number (Z) but different mass numbers (A).

\[L=mvr=\frac{nh}{2\pi},\quad n=1,2,3\ldots\]

\[h\nu=E_2-E_1=\frac{hc}{\lambda}\]

The average atomic mass accounts for the different isotopes of an element and their natural abundances.

\[M_{\mathrm{avg.}}=\frac{M_{1}\times r_{1}+M_{2}\times r_{2}+M_{3}\times r_{3}}{r_{1}+r_{2}+r_{3}}\]

where M₁, M₂, M₃ are atomic masses of isotopes and r₁, r₂, r₃ are their relative abundances.

Bohr's First Postulate:
An atom consists of a small, massive central core called the nucleus, around which planetary electrons revolve. The centripetal force required for their rotation is provided by the electrostatic attraction between the electrons and the nucleus.

Bohr's Second Postulate (Quantum Condition):
The electrons are permitted to circulate only in those orbits in which the angular momentum of an electron is an integral multiple of \[\frac{h}{2\pi}\]; h being Planck's constant.

Bohr's Third Postulate:
While revolving in the permissible orbits, an electron does not radiate energy. These non-radiating orbits are called stationary orbits.

Bohr's Fourth Postulate:
An atom can emit or absorb radiation in the form of discrete energy photons only when an electron jumps from a higher to a lower orbit or from a lower to a higher orbit, respectively.

Five fundamental laws govern how elements and compounds combine chemically:

Law 1 — Law of Conservation of Mass (Antoine Lavoisier)

Mass is neither created nor destroyed during any chemical reaction. The total mass of reactants always equals the total mass of products.

Law 2 — Law of Definite Proportion (Joseph Proust)

A specific chemical compound always contains its elements combined in a fixed ratio by weight, regardless of where the compound comes from or how it was made.

Exception: This law does not hold for compounds made from different isotopes of an element.

Law 3 — Law of Multiple Proportion (John Dalton)

When two elements combine to form more than one compound, the different masses of one element that combine with a fixed mass of the other are always in a simple whole-number ratio. Example: CO and CO₂.

Law 4 — Gay Lussac's Law of Gaseous Volumes

When gases react or are produced in a chemical reaction, their volumes bear a simple whole-number ratio to each other — provided temperature and pressure remain the same.

Law 5 — Avogadro's Law

At the same temperature and pressure, equal volumes of all gases contain the same number of molecules, regardless of the type of gas.

"When two elements combine to form more than one compound, the masses of one element that combine with a fixed mass of the other are in a simple whole number ratio."

• Proposed by Dalton in 1803.
• e.g. Hydrogen + Oxygen forms water (H₂O) and hydrogen peroxide (H₂O₂). With 2 g of H, oxygen combines as 16 g and 32 g → ratio = 1:2.

"The ratio in which two elements A and B separately combine with a fixed mass of a third element C is either the same as, or a simple multiple of, the ratio in which A and B combine directly with each other."

• Also called the Law of Equivalences.
• e.g. Carbon and sulfur both combine with oxygen; the ratio in which they combine with oxygen is related to the ratio in which they combine with each other.

• Proposed by Ernest Rutherford in 1911 based on the gold foil (α-particle scattering) experiment.
• Most α-particles passed straight through, showing that the atom is mostly empty space.
• Some α-particles were deflected, indicating the presence of a positively charged centre.
• Very few α-particles were deflected at large angles or bounced back, proving a dense nucleus.
• All the positive charge and most of the mass are concentrated in a tiny nucleus (~10⁻¹⁵ m).
• Electrons revolve around the nucleus in circular orbits.
• The electrostatic force of attraction between nucleus and electrons keeps them in orbit.
• Limitation: Could not explain stability of atom and line spectra of hydrogen.

• Bohr modified Rutherford's model - electrons move in fixed orbital shells, each with fixed energy levels.
• The centripetal force for electron revolution is provided by electrostatic attraction between the electron and the nucleus.
• An electron does not radiate energy while revolving in a stationary orbit.
• Energy is emitted or absorbed only during electron transitions between orbits.
• Limitations of Bohr's Model:
• Fails to explain the Zeeman Effect (effect of high magnetic fields on atomic spectra).
• Contradicts the Heisenberg Uncertainty Principle.
• Unable to explain the spectra of larger/multi-electron atoms.

• Discovered by James Chadwick (1932)
• Charge = 0 (neutral)
• Mass = 1.675 × 10⁻²⁷ kg (almost equal to proton)
• Present in the nucleus along with protons
• Responsible for isotopes and atomic mass

Reaction: \[_4^9Be+_2^4He\to_6^{12}C+_0^1n\]

• The structure of an atom and its nucleus was developed from the discovery of electrons by J.J. Thomson and alpha particle scattering experiments by Rutherford.
• An atom consists of electrons, protons, and neutrons, with protons and neutrons in the nucleus and electrons revolving in stationary orbits.
• The maximum number of electrons in a shell is given by 2n², and the shells are named K, L, M, N, O, P, and Q.

Isotopes are atoms of the same element that have the same atomic number but different mass numbers (different number of neutrons).

Same in isotopes:

• Atomic number (Z)
• Number of protons and electrons
• Electronic configuration
• Position in periodic table
• Chemical properties (nearly identical)

Different in isotopes:

• Mass number (A)
• Number of neutrons
• Physical properties

Examples: \[_1H^1and_1H^2\]