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Question
Write a note on homologous series.
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Solution
A series of organic compounds each containing a characteric functional group and the successive members differ from each other in a molecular formula by a CH2 group is called homologous series.
Example:
- Alkanes:
Methane (CH4), Ethane (C2H6), Propane (C3H8) etc.. - Alcohols:
Methanol (CH3OH), Ethanol (C2H5OH) Propanol (C3H7OH) etc…
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Draw a formula for the first five members of the homologous series beginning with the given compound.
H–CH=CH2
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\[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3} \ce{CH3}\phantom{..............}
\end{array}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3}\phantom{..}\ce{CH3}\phantom{..............}\\
\end{array}\]
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\[\ce{CH2 = CH - CH2 - CH3}\]
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\[\begin{array}{cc}
\ce{CH3}\phantom{..................}\\
|\phantom{....................}\\
\ce{CH3 - C - CH - CH2 - CH2 - CH3}\\
|\phantom{....}|\phantom{................}\\
\ce{CH3}\phantom{.}\ce{CH3}\phantom{..............}
\end{array}\]
