English
Tamil Nadu Board of Secondary EducationHSC Science Class 12

Why is AC current used instead of DC in measuring the electrolytic conductance? - Chemistry

Advertisements
Advertisements

Question

Why is AC current used instead of DC in measuring the electrolytic conductance?

Answer in Brief
Advertisements

Solution

1. AC current to prevent electrolysis of the solution.

2. If we apply DC current to the cell the positive ions will be attracted to the negative plate and the negative ions to the positive plate. This will cause the composition of the electrolyte to change while measuring the equivalent conductance.

3. So DC current through the conductivity cell will lead to the electrolysis of the solution taken in the cell. To avoid such electrolysis, we have to use AC current for measuring equivalent conductance.

shaalaa.com
Conductivity of Electrolytic Solution
  Is there an error in this question or solution?
Chapter 9: Electro Chemistry - Evaluation [Page 66]

APPEARS IN

Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 12 TN Board
Chapter 9 Electro Chemistry
Evaluation | Q 11. | Page 66

RELATED QUESTIONS

The molar conductivity of a 0.5 mol dm−3 solution of AgNO3 with electrolytic conductivity of 5.76 × 10−3 S cm−1 at 298 K is ____________.


Electrolyte KCl KNO3 HCl NaOAC NaCl
Λ_
(S cm mol−1)
149.9 145.0 426.2 91.0 126.5

Calculate \[\ce{Λ^∘_{HOAC}}\] using appropriate molar conductances of the electrolytes listed above at infinite dilution in water at 25°C.


Which of the following electrolytic solution has the least specific conductance?


The equivalent conductance of `"M"/36` solution of a weak monobasic acid is 6 mho cm2 equivalent−1 and at infinite dilution is 400 mho cm2 equivalent−1. The dissociation constant of this acid is ____________.


A conductivity cell has been calibrated with a 0.01 M, 1 : 1 electrolytic solution (specific conductance (κ = 1.25 × 10−3 S cm−1) in the cell and the measured resistance was 800 Ω at 25°C. The cell constant is, ____________.


Why does the conductivity of a solution decrease on dilution of the solution?


The conductivity of a 0.01 M solution of a 1 : 1 weak electrolyte at 298 K is 1.5 × 10−4 S cm−1.

i) molar conductivity of the solution

ii) degree of dissociation and the dissociation constant of the weak electrolyte

Given that

\[\ce{λ^∘_{cation}}\] = 248.2 S cm2 mol−1

\[\ce{λ^∘_{anion}}\] = 51.8 S cm2 mol−1


Which of 0.1 M HCl and 0.1 M KCl do you expect to have greater `Λ_"m"^∘` and why?


Arrange the following solutions in the decreasing order of specific conductance.

i) 0.01 M KCl

ii) 0.005 M KCl

iii) 0.1 M KCl

iv) 0.25 M KCl

v) 0.5 M KCl


0.1 M NaCl solution is placed in two different cells having cell constant 0.5 and 0.25 cm−1 respectively. Which of the two will have a greater value of specific conductance.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×