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What is Nessler’s reagent? - Chemistry

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Question

What is Nessler’s reagent?

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Solution

  • Nessler's reagent is a solution of mercury(II) iodide (HgI2) in potassium iodide (KI) and potassium hydroxide (KOH) named after the German chemist Julius Nessler.
  • Nessler’s reagent is an alkaline solution of K2 HgI4.
  • It is used in testing for ammonia, with which it forms a brown colouration or precipitate.

\[\ce{NH3 + 2[HgI4]^2- + 4OH^- → HgO.Hg(NH2) + 7I^- + 3H2O}\]

  • Low ammonia: Yellow coloration

  • High ammonia: Reddish-brown precipitate

This color change confirms the presence of ammonia.

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2018-2019 (March) Set 1

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