English

What do you observe when caustic soda solution is added to the following solution, first a little and then in excess: ZnSO4 Write a balanced equation for this reaction.

Advertisements
Advertisements

Question

What do you observe when caustic soda solution is added to the following solution, first a little and then in excess:

ZnSO4

Write a balanced equation for this reaction.

Short/Brief Note
Advertisements

Solution

\[\ce{\underset{\text{Colourless}}{ZnSO4} + 2NaOH -> \underset{\text{white gelatinous ppt.}}{Zn(OH)2↓} + \underset{\text{Colourless}}{Na2SO4}}\]

In excess of alkali , White gelatinous ppt. of Zn(OH)2 becomes soluble :

\[\ce{Zn(OH)2 + 2NaOH(excess) -> \underset{\text{Sodium Zincate (Colourless)}}{Na2ZnO2 + 2H2O}}\]

shaalaa.com
Action of Sodium Hydroxide Solution on Certain Metallic Salt Solutions
  Is there an error in this question or solution?
Chapter 4: Analytical Chemistry - EXERCISE-4 [Page 73]

APPEARS IN

S.P. Singh Concise Chemistry [English] Class 10 ICSE
Chapter 4 Analytical Chemistry
EXERCISE-4 | Q (C) 3. (b) | Page 73

RELATED QUESTIONS

Name a white, insoluble oxide that dissolves when fused with caustic soda or caustic potash.


Using sodium hydroxide solution, how will you distinguish:
Lead hydroxide from magnesium hydroxide.


Sodium hydroxide solution is added to solution A. A white precipitate is formed which is soluble in excess sodium hydroxide. Name the metal ion present in A.


Using Sodium hydroxide solution, how would you distinguish: Ammonium sulphate from sodium sulphate.


Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).

Aqueous salt solution Colour of precipitate when NaOH is added in a small quantity Nature of precipitate (soluble or insoluble) when NaOH is added in excess
Copper (II) sulphate (i) (vi)
Zinc nitrate (ii) (vii)
Lead nitrate (iii) (viii)
Calcium chloride (iv) (ix)
Iron (III) Sulphate (v) (x)

Sodium hydroxide solution is added to the solutions containing the ions mentioned in List X. List Y gives the details of the precipitate. Match the ions with their coloured precipitates.

List X List Y
(i) Pb2+ (A) Reddish Brown
(ii) Fe2+ (B) White insoluble inexcess
(iii) Zn2+ (C) Dirty green
(iv) Fe3+ (D) White soluble in excess
(v) Cu2+ (E) White soluble in excess
(vi) Ca2+ (F) Blue

Distinguish by adding:

Sodium hydroxide solution and ammonium hydroxide solution to calcium salt solution and lead salt solution.


Distinguish by adding:

Sodium hydroxide solution and ammonium hydroxide solution to lead nitrate solution and zinc nitrate solution.


Distinguish by adding:

Sodium hydroxide solution and ammonium hydroxide solution to copper salt solution and ferrous salt solution.


Aqueous lead (II) nitrate can be distinguished from aqueous zinc nitrate by adding any of the following solutions in excess, except:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×