English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Use the data given in below find out which option the order of reducing power is correct. E0cr2O12-Cr3+ = 1.33 V E0Cl2Cl- = 1.36 V E0MnO4-MN2+ = 1.51 V E0Cr3+Cr = – 0.74 V - Chemistry

Advertisements
Advertisements

Question

Use the data given in below find out which option the order of reducing power is correct.

`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V

`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V

Options

  • \[\ce{Cr^{3+} < Cl– < Mn^{2+} < Cr}\]

  • \[\ce{Mn^{2+} < Cl– < Cr^{3+} < Cr}\]

  • \[\ce{Cr^{3+} < Cl– < Cr_2O_7^{2–} < MnO^{-}4}\]

  • \[\ce{Mn2+ < Cr3+ < Cl– < Cr}\]

MCQ
Advertisements

Solution

\[\ce{Mn^{2+} < Cl– < Cr^{3+} < Cr}\]

Explanation:

Lower the value of standard reduction potential greater will be the reducing power.

shaalaa.com
  Is there an error in this question or solution?
Chapter 3: Electrochemistry - Exercises [Page 35]

APPEARS IN

NCERT Exemplar Chemistry [English] Class 12
Chapter 3 Electrochemistry
Exercises | Q I. 10. | Page 35

RELATED QUESTIONS

Among Zn and Cu, which would occur more readily in nature as metal and which as an ion?


If 'I' stands for the distance between the electrodes and 'a' stands for the area of cross-section of the electrode, `"l"/"a"` refers to ____________.


What is the SI unit tor electrochemical equivalent?


At 25°C, the emf of the following electrochemical cell.

\[\ce{Ag_{(s)} | Ag^+ (0.01 M) | | Zn^{2+} {(0.1 M)} | Zn_{(s)}}\] will be:

(Given \[\ce{E^0_{cell}}\] = −1.562 V)


How many faradays of electricity are required for the following reaction to occur

\[\ce{MnO^-_4 -> Mn^2+}\]


A certain current liberated 0.504 gm of hydrogen in 2 hours. How many grams of copper can be liberated by the same current flowing for the same time through copper sulphate solution.


Define anode


A copper electrode is dipped in 0.1 M copper sulphate solution at 25°C. Calculate the electrode potential of copper.
[Given: \[\ce{E^0_{{Cu^{2+}|Cu}}}\] = 0.34 V]


Electrode potential for Mg electrode varies according to the equation

`E_(Mg^(2+)  |  Mg) = E_(Mg^(2+)  |  Mg)^Θ - 0.059/2 log  1/([Mg^(2+)])`. The graph of `E_(Mg^(2+)  |  Mg)` vs `log [Mg^(2+)]` is ______.


The quantity of charge required to obtain one mole of aluminium from Al2O3 is ______.


For the given cell, \[\ce{Mg | Mg^{2+} || Cu^{2+} | Cu}\]

(i) \[\ce{Mg}\] is cathode

(ii) \[\ce{Cu}\] is cathode

(iii) The cell reaction is \[\ce{Mg^+ Cu^{2+} -> Mg^{2+} + Cu}\]

(iv) \[\ce{Cu}\] is the oxidising agent


Consider the following diagram in which an electrochemical cell is coupled to an electrolytic cell. What will be the polarity of electrodes ‘A’ and ‘B’ in the electrolytic cell?


How will the pH of brine (aq. \[\ce{NaCl}\] solution) be affected when it is electrolysed?


Match the items of Column I and Column II.

Column I Column II
(i) K (a) I × t
(ii) Λm (b) `Λ_m/Λ_m^0`
(iii) α (c) `K/c`
(iv) Q (d) `G^∗/R`

Assertion: ECell should have a positive value for the cell to function.

Reason: `"E"_("cathode") < "E"_("anode")`


Standard reduction electrode potentials of three metals A, B and C are respectively + 0.5 V, – 3.0 V. and – 1.2 V. The reducing powers of there metal is.


The number of moles of electrons passed when the current of 2 A is passed through a solution of electrolyte for 20 minutes is ______.


Galvanic cell is a device in which ______.


State the term for the following:

Two metal plates or wires through which the current enters and leaves the electrolytic cell.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×