Advertisements
Advertisements
Question
The light emitted in the transition n = 3 to n = 2 in hydrogen is called Hα light. Find the maximum work function a metal can have so that Hα light can emit photoelectrons from it.
Advertisements
Solution
The Hα light can emit the photoelectrons if its energy is greater than or equal to the work function of the metal.
Energy possessed by Hα light (E) is given by
`E = 13.6 (1/n_1^2 - 1/n_2^2)eV`
`Here , n_1 = 2 , n_2 = 3`
`therefore E = 13.6 xx (1/4 - 1/4 )`
= `(13.6xx5)/36 = 1.89 eV`
= 1.90 eV
Hα light will be able to emit electron from the metal surface for the maximum work function of metal to be 1.90 eV.
APPEARS IN
RELATED QUESTIONS
(i) State Bohr's quantization condition for defining stationary orbits. How does the de Broglie hypothesis explain the stationary orbits?
(ii) Find the relation between three wavelengths λ1, λ2 and λ3 from the energy-level diagram shown below.

State Bohr’s postulate of hydrogen atom which successfully explains the emission lines in the spectrum of hydrogen atom. Use Rydberg formula to determine the wavelength of Hα line. [Given: Rydberg constant R = 1.03 × 107 m−1]
Draw a neat, labelled energy level diagram for H atom showing the transitions. Explain the series of spectral lines for H atom, whose fixed inner orbit numbers are 3 and 4 respectively.
Calculate the energy required for the process
\[\ce{He^+_{(g)} -> He^{2+}_{(g)} + e^-}\]
The ionization energy for the H atom in the ground state is 2.18 ×10–18 J atom–1
On the basis of Bohr's theory, derive an expression for the radius of the nth orbit of an electron of the hydrogen atom.
State Bohr postulate of hydrogen atom that gives the relationship for the frequency of emitted photon in a transition.
Using Bohr’s postulates, obtain the expressions for (i) kinetic energy and (ii) potential energy of the electron in stationary state of hydrogen atom.
Draw the energy level diagram showing how the transitions between energy levels result in the appearance of Lymann Series.
Find the wavelength of the radiation emitted by hydrogen in the transitions (a) n = 3 to n= 2, (b) n = 5 to n = 4 and (c) n = 10 to n = 9.
The dissociation constant of a weak base (BOH) is 1.8 × 10−5. Its degree of dissociation in 0.001 M solution is ____________.
According to Bohr's theory, an electron can move only in those orbits for which its angular momentum is integral multiple of ____________.
Calculate the energy and frequency of the radiation emitted when an electron jumps from n = 3 to n = 2 in a hydrogen atom.
Why was a change in the Bohr Model of atom required? Due to which important development (s), concept of movement of an electron in an orbit was replaced by, the concept of probability of finding electron in an orbital? What is the name given to the changed model of atom?
If a proton had a radius R and the charge was uniformly distributed, calculate using Bohr theory, the ground state energy of a H-atom when (i) R = 0.1 Å, and (ii) R = 10 Å.
According to Bohr atom model, in which of the following transitions will the frequency be maximum?
A hydrogen atom in is ground state absorbs 10.2 eV of energy. The angular momentum of electron of the hydrogen atom will increase by the value of ______.
(Given, Planck's constant = 6.6 × 10-34 Js)
In hydrogen atom, transition from the state n = 6 to n = 1 results in ultraviolet radiation. Infrared radiation will be obtained in the transition ______.
What is the energy of an electron in stationary state corresponding to n = 2?
On the basis of Bohr's theory, derive an expression for the radius of the nth orbit of an electron of hydrogen atom.
State the Bohr's postulate of angular momentum of an electron.
Calculate the radius of the second orbit of He+.
