Advertisements
Advertisements
Questions
How would you account for the following:
The chemistry of actinoids is more complicated as compared to lanthanoids.
Chemistry of actinoids is complicated as compared to lanthanoids. Give two reasons.
Why is the chemistry of actinoids complicated as compared to lanthanoids?
Advertisements
Solution 1
The energy difference between the 6d, 7s and 5f orbitals is very small in actinoids. In addition, the 5f orbitals of the actinoids are less shielded than the 4f orbitals of the lanthanoids. Thus, in the lanthanoids, only 4f electrons of Ce participate in chemical bonding, whereas in the lighter actinoids, up to americium, the 5f electrons also take part. This makes the chemistry of actinoids more complicated than that of lanthanoids
Solution 2
The reasons are as follows:
- Actinoids display a large number of oxidation states, while lanthanoids primarily show only three oxidation states.
- Actinoids are radioactive in nature.
APPEARS IN
RELATED QUESTIONS
Why do actinoids show a wide range of oxidation states?
Write one similarity and one difference between the chemistry of lanthanoid and actinoid elements.
How would you account the following :
Highest fluoride of Mn is MnF4 whereas the highest oxide is Mn2O7.
Give reasons for the following:
The chemistry of actinoids elements is not so smooth as that of the lanthanoids.
Choose the most correct option.
In which of the following series all the elements are radioactive in nature?
Identify the CORRECT statement.
The electronic configuration of Ux+ ion is [Rn]. What is the value of x?
[At. No. of U = 92]
Which among the following elements is radioactive?
Maximum oxidation state exhibited by Chlorine is ______.
Which of the following actinoids show oxidation states upto +7?
(i) Am
(ii) Pu
(iii) U
(iv) Np
