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प्रश्न
How would you account for the following:
The chemistry of actinoids is more complicated as compared to lanthanoids.
Chemistry of actinoids is complicated as compared to lanthanoids. Give two reasons.
Why is the chemistry of actinoids complicated as compared to lanthanoids?
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उत्तर १
The energy difference between the 6d, 7s and 5f orbitals is very small in actinoids. In addition, the 5f orbitals of the actinoids are less shielded than the 4f orbitals of the lanthanoids. Thus, in the lanthanoids, only 4f electrons of Ce participate in chemical bonding, whereas in the lighter actinoids, up to americium, the 5f electrons also take part. This makes the chemistry of actinoids more complicated than that of lanthanoids
उत्तर २
The reasons are as follows:
- Actinoids display a large number of oxidation states, while lanthanoids primarily show only three oxidation states.
- Actinoids are radioactive in nature.
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संबंधित प्रश्न
Give a reason for the following:
Actinoids show irregularities in their electronic configurations.
Why do actinoids show a wide range of oxidation states?
Write on similarity between the chemistry of lanthanoids and actinoids.
Which is the last element in the series of the actinoids? Write the electronic configuration of this element. Comment on the possible oxidation state of this element.
Compare the chemistry of the actinoids with that of lanthanoids with reference to electronic configuration
What is the position of actinoids in periodic table ?
Choose the most correct option.
In which of the following series all the elements are radioactive in nature?
Manganese in the +2 oxidation state is more stable than +3 oxidation state where as iron is stable at +3 oxidation state than +2 oxidation state. Explain why?
Which of the following oxidation state is common for all lanthanoids?
Which of the following actinoids show oxidation states upto +7?
(i) Am
(ii) Pu
(iii) U
(iv) Np
