English

Select the most appropriate option. If the standard enthalpy of formation of methanol is –238.9 kJ mol–1 then entropy change of the surroundings will be _______. - Chemistry

Advertisements
Advertisements

Question

Select the most appropriate option.

If the standard enthalpy of formation of methanol is –238.9 kJ mol–1 then entropy change of the surroundings will be _______. 

Options

  • –801.7 J K–1

  • 801.7 J K–1

  • 0.8017 J K–1

  • –0.8017 J K–1

MCQ
Advertisements

Solution

If the standard enthalpy of formation of methanol is –238.9 kJ mol–1 then entropy change of the surroundings will be 801.7 J K–1.

Explanation:

For standard state, temperature = 298 K

`triangle "S"_"surr" = - (triangle "H")/"T" = - ((- 238.9  "kJ"))/(298 "k")`

= + 0.8017 kJ K-1

= 801.7 J K-1 

shaalaa.com
  Is there an error in this question or solution?
Chapter 4: Chemical Thermodynamics - Exercises [Page 87]

APPEARS IN

Balbharati Chemistry [English] Standard 12 Maharashtra State Board
Chapter 4 Chemical Thermodynamics
Exercises | Q 1.07 | Page 87

RELATED QUESTIONS

Select the most appropriate option.

The enthalpy of formation for all elements in their standard states is _______.


Select the most appropriate option.

Bond enthalpies of H–H, Cl–Cl, and H–Cl bonds are 434 kJ mol–1, 242 kJ mol–1, and 431 kJ mol–1, respectively. Enthalpy of formation of HCl is _______.


Answer in brief.

Obtain the expression for work done in chemical reaction.


Obtain the relationship between ΔH and ΔU for gas phase reactions.


Calculate the amount of work done in the

1) Oxidation of 1 mole HCl(g) at 200 °C according to reaction.

4HCl(g) + O2(g) → 2Cl2(g) + 2H2O(g)

2) Decomposition of one mole of NO at 300 °C for the reaction

2NO(g) → N2(g) + O2(g)


Answer the following question.

When 6.0 g of O2 reacts with CIF as per 

\[\ce{2ClF_{(g)} + O2_{(g)} -> Cl2O_{(g)} + OF2_{(g)}}\]

The enthalpy change is 38.55 kJ. What is the standard enthalpy of the reaction? (Δr H° = 205.6 kJ)


Calculate the standard enthalpy of formation of \[\ce{CH3OH_{(l)}}\] from the following data:

\[\ce{CH3OH_{(l)} + 3/2 O2_{(g)} -> CO2_{(g)} + 2H2O_{(l)} }\]; ΔrH° = − 726 kJ mol-1 

\[\ce{C_{(graphite)} + O2_{(g)} -> CO2_{(g)}}\]; ΔcH° = −393 kJ mol−1

\[\ce{H2_{(g)} + 1/2 O_{(g)} -> H2O_{(l)}}\]; ΔfH° = −286 kJ mol−1


An ideal gas expands from the volume of 1 × 10–3 m3 to 1 × 10–2 m3 at 300 K against a constant pressure at 1 × 105 Nm–2. The work done is


The work done by the liberated gas when 55.85 g of iron (molar mass 55.85 g mol–1) reacts with hydrochloric acid in an open beaker at 25°C


Calculate the enthalpy change for the reaction \[\ce{Fe2O3 + 3CO -> 2Fe + 3CO2}\] from the following data.

\[\ce{2Fe + 3/2O2 -> Fe2O3}\]; ΔH = −741 kJ

\[\ce{C + 1/2O2 -> CO}\]; ΔH = −137 kJ

\[\ce{C + O2-> CO2}\]; ΔH = −394.5 kJ


The standard enthalpies of formation of SO2 and SO3 are −297 kJ mol−1 and −396 kJ mol−1 respectively. Calculate the standard enthalpy of reaction for the reaction: \[\ce{SO2 + 1/2O2 -> SO3}\]


For which of the following ∆U = ∆H?


When 6.0 g of O2 reacts with CIF as per \[\ce{2ClF_{(g)} + O2_{(g)} -> Cl2O_{(g)} + OF2_{(g)}}\] the enthalpy change is 38.55 kJ. The standard enthalpy of the reaction is ____________.


Identify the equation in which change in enthalpy is equal to change in internal energy.


When 4 g of iron is burnt to ferric oxide at constant pressure, 29.28 kJ of heat is evolved. What is the enthalpy of formation of ferric oxide?

(Atomic mass of Fe = 56)


The enthalpy change for two reactions are given by the equations

\[\ce{2Cr_{(s)} + 1.5 O2_{(g)} -> Cr2O3_{(s)}}\];

∆H1 = −1130 kJ ............(i)

\[\ce{C_{(s)} + 0.5 O2_{(g)} -> CO_{(g)}}\];

∆H2 = −110 kJ .........(ii)

What is the enthalpy change, in kJ, for the following reaction?

\[\ce{3C_{(s)} + Cr2O3_{(s)} -> 2Cr_{(s)} + 3CO_{(g)}}\]


In which of the following reactions does the heat change represent the heat of formation of water?


In which of the following reactions, ∆H is greater than ∆U?


For the reaction, \[\ce{A_{(s)} + 2B_{(g)} -> 5C_{(s)} + D_{(l)}}\], ∆H and ∆U are related as ____________.


If 2 kJ of heat is released from system and 6 kJ of work is done on the system, what is enthalpy change of system?


The work done during combustion of 9 × 10-2 kg of ethane, C2H6 (g) at 300 K is ______.
(Given R = 8.314 J deg-1, atomic mass C = 12, H = 1)


Calculate the work done in oxidation of so2(g) at 25°C if, \[\ce{2SO_{2(g)} + O2_{(g)} -> 2SO_{3(g)}}\], R = 8.314 J K−1 mol−1.


In a particular reaction, 2 kJ of heat is released by the system and 8 kJ of work is done on the system. Determine ΔU.


Calculate work done in oxidation of 4 moles of SO2 at 25°C. (Given: R = 8.314 JK−1 mol−1 ).


Calculate the standard entropy change of the surrounding if standard enthalpy of formation of methyl alcohol is –240 kJ mol-1.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×