Advertisements
Advertisements
Questions
On the basis of crystal field theory, write the electronic configuration for d4 ion if ∆0 < P.
Write the electronic configuration for d4 ion if ∆0 < P on the basis of crystal field theory.
Advertisements
Solution
On the basis of crystal field theory, for a d4 ion, if Δ0 < P, then the complex is a high spin complex formed by the association of weak field ligands with the metal ion. As a result, the fourth electron enters one of the eg orbitals, thereby, exhibiting the electronic configuration \[\ce{t_2g ^3eg^1}\].
APPEARS IN
RELATED QUESTIONS
How are the following conversions carried out?
Benzoic acid into metanitrobenzoic acid.
Why are low spin tetrahedral complexes rarely observed?
The CFSE for octahedral [CoCl6]−4 is 18,000 cm−1. What will be the CFSE for tetrahedral [CoCl3]−2?
In a coordination entity, the electronic configuration of the central metal ion is t2g3 eg1
Draw the crystal field splitting diagram for the above complex.
The CFSE of [CoCl6]3– is 18000 cm–1 the CFSE for [CoCl4]– will be ______.
The correct order of intensity of colors of the compounds is ______.
Consider that d6 metal ion (M2+) forms a complex with aqua ligands and the spin only magnetic moment of the complex is 4.90 BM. The geometry and the crystal field stabilization energy of the complex are ______.
The complex that has highest crystal field splitting energy (Δ) is ______.
On the basis of Crystal Field Theory, write the electronic configuration of d4 ion if Δ0 > P.
The value of the spin only magnetic moment for one of the following configurations is 2.84 BM. The correct one is:
