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Match the salts underlined in Column A with the most suitable method of preparation given in Column B. Column A (a) ZnCl2 from Zn (b) KNO3 from KOH. (c) CaCO3 from CaCl2.

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Question

Match the salts underlined in Column A with the most suitable method of preparation given in Column B.

  Column A   Column B
(a) \[\ce{ZnCl2 \text{from} Zn}\] 1. Precipitation
(b) \[\ce{KNO3 \text{from} KOH}\]. 2. Direct combination
(c) \[\ce{CaCO3 \text{from} CaCl2}\]. 3. Displacement reaction
    4. Neutralization
Match the Columns
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Solution

  Column A   Column B
(a) \[\ce{ZnCl2 \text{from} Zn}\] 3. Displacement reaction
(b) \[\ce{KNO3 \text{from} KOH}\]. 4. Neutralization
(c) \[\ce{CaCO3 \text{from} CaCl2}\]. 1. Precipitation

Explanation:

  1. Displacement Reaction
    \[\ce{Zn + HCl -> ZnCl2 + H2}\]
    Displace H from HCl because zinc is more reactive than hydrogen.
  2. Neutralization Reaction
    \[\ce{KOH + HNO3 -> KNO3 + H2O}\]
    \[\ce{Base + Acid -> Salt + water; Neutralization reaction}\]
  3. Precipitation Reaction
    \[\ce{CaCl2 + Na2CO3 -> 2NaCl + CaCO3 ↓}\]
    Sodium chloride and a clacium carbonate precipitate follow from the double displacement reaction.
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