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How would you convert carbon tetrachloride to chloroform?

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Question

How would you convert carbon tetrachloride to chloroform?

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Solution

To convert carbon tetrachloride (CCl4) to chloroform ((CHCl3), you must perform a partial reduction of carbon tetrachloride. In this reaction, one of the chlorine atoms is replaced by a hydrogen atom.

\[\ce{\underset{tetrachloride}{\underset{carbon}{CCl4}} + 2[H] ->[Fe/HCl][]\underset{chloroform}{CHCl3} + HCl}\]

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Chapter 6: Haloalkanes and Haloarenes - REVIEW EXERCISES [Page 593]

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Nootan Chemistry [English] Class 12 ISC
Chapter 6 Haloalkanes and Haloarenes
REVIEW EXERCISES | Q 10.43 (ii) | Page 593
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