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Questions
How will you convert the following?
Aniline into N−phenylethanamide
Complete and write chemical equations for the following reaction:
Aniline into N-Phenylethanamide
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Solution
Aniline into N-phenylethanamide

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(CH3CO)2O/pyridine
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Assertion: N, N-Diethylbenzene sulphonamide is insoluble in alkali.
Reason: Sulphonyl group attached to nitrogen atom is strong electron-withdrawing group.
Give reasons for the following observation:
Aniline is acetylated before nitration reaction.
Assertion (A): Bromination of benzoic acid, gives m-bromobenzoic acid.
Reason (R): Carboxyl group increases the electron density at the meta position.
Aniline does not give Friedel-Crafts reaction. Give a reason.
Identify the major product C formed in the following reaction sequence:
\[\ce{CH3 - CH2 - CH2 - I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH][Br2] \underset{(major)}{C}}\]
