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How is Phosphine Prepared Using the Following Reagent? Caustic Soda - Chemistry

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Question

How is phosphine prepared using the following reagent?

Caustic soda

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Solution

Preparation of Phosphine using Caustic soda (NaOH)
White phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO2. It is the laboratory method.

`P_4  +       3NaOH+3H_2O     ->  PH_3  +     3NaH_2PO_2`

White        Sodium hydroxide   Phosphine     Sodium
phosphorus                                                      hypophosphite

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2016-2017 (March)

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