Advertisements
Advertisements
Question
How does solubility of a gas in water varies with the temperature?
Advertisements
Solution
Effect of temperature:
According to Charle’s law, volume of a given mass of a gas increases with increase in
temperature. Therefore, volume of a given mass of dissolved gas in solution also increases with increase in temperature, so that it becomes impossible for the solvent in solution to accommodate gaseous solute in it and gas bubbles out. Hence solubility of gas in liquid decreases with increase of temperature.
APPEARS IN
RELATED QUESTIONS
Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of KH (Henry’s constant) and why
Henry’s law constant for CO2 in water is 1.67 × 108 Pa at 298 K. Calculate the quantity of CO2 in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K.
The partial pressure of ethane over a solution containing 6.56 × 10−3 g of ethane is 1 bar. If the solution contains 5.00 × 10−2 g of ethane, then what shall be the partial pressure of the gas?
Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain.
Cyclohexane, KCl, CH3OH, CH3CN
Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg. Calculate the solubility of methane in benzene at 298 K under 760 mm Hg.
The air is a mixture of a number of gases. The major components are oxygen and nitrogen with approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K if the Henry’s law constants for oxygen and nitrogen are 3.30 × 107 mm and 6.51 × 107 mm respectively, calculate the composition of these gases in water.
Which mixture is used for respiration by deep sea divers?
(A) He + O2
(B) Ne + O2
(C) Ar + O2
(D) Kr + O2
The solubility product of PbCl2 at 298K is 1.7 × 10-5. Calculate the solubility of PbCl2 in g/lit. at 298K.
Atomic Weights: [Pb = 207 and Cl = 35.5]
A solution is prepared by dissolving 9.25 g of non-volatile solute in 450 mL of water. It has an osmotic pressure of 350 mm of Hg at 27°C. Assuming the solute is non-electrolyte, determine its molecular mass. (R = 0.0821 Lit-atm K−1 mol−1)
Write the name of gas released when Cu is added to dilute HNO3
Write the name of gas released when Cu is added to the conc. HNO3
The statement “If 0.003 moles of a gas are dissolved in 900 g of water under a pressure of 1 atmosphere, 0.006 moles will be dissolved under a pressure of 2 atmospheres”, illustrates.
Henry’s law constant of oxygen is 1.4 × 10–3 mol lit–1 atm–1 at 298 K. How much of oxygen is dissolved in 100 ml at 298 K when the partial pressure of oxygen is 0.5 atm?
Value of Henry's constant KH ______.
Which of the following factor(s) affect the solubility of a gaseous solute in the fixed volume of liquid solvent?
(a) nature of solute
(b) temperature
(c) pressure
(i) (a) and (c) at constant T
(ii) (a) and (b) at constant P
(iii) (b) and (c) only
(iv) (c) only
Solubility of gases in liquids decreases with rise in temperature because dissolution is an ______.
Explain the following phenomena with the help of Henry’s law.
Painful condition known as bends.
The solubility of a gas in water depends on ______
State Henry’s law and explain why are the tanks used by scuba divers filled with air diluted with helium (11.7% helium, 56.2% nitrogen and 32.1% oxygen)?
If O2 gas is bubbled through water at 303 K, the number of millimoles of O2 gas that dissolve in 1 litre of water is ______. (Nearest integer)
(Given: Henry's Law constant for O2 at 303 K is 46.82 k bar and partial pressure of O2 = 0.920 bar)
(Assume solubility of O2 in water is too small, nearly negligible)
Solubility of gas in liquid decreases with increase in ______.
Identify that the following compound is insoluble, partially soluble and highly soluble in water.
phenol
Identify that the following compound is insoluble, partially soluble and highly soluble in water.
Toluene
Identify that the following compound is insoluble, partially soluble or highly soluble in water:
Chloroform
