Advertisements
Advertisements
Question
Give reasons: SO2 is reducing while TeO2 is an oxidising agent.
Advertisements
Solution
In case of sulphur, because of the presence of empty d-orbital, it can expand its oxidation state from the + 4 to the +6 oxidation state. Hence, it acts as a reducing agent.
Te is a heavy element and so because of the inert pair effect, the lower oxidation state is more stable. Hence, it acts as an oxidising agent.
APPEARS IN
RELATED QUESTIONS
Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.
Knowing the electron gain enthalpy values for \[\ce{O -> O-}\] and \[\ce{O -> O^{2-}}\] as −141 and 702 kJ mol−1 respectively, how can you account for the formation of a large number of oxides having O2− species and not O−?
(Hint: Consider lattice energy factor in the formation of compounds).
Explain the following properties of group 16 elements :
1) Electro negativity
2) Melting and boiling points
3) Metallic character
4) Allotropy
Arrange the following in order of the property indicated set.
HF, HCl, HBr, HI - decreasing bond enthalpy.
The boiling points of hydrides of group 16 are in the order:
The formation of \[\ce{O^+_2[PtF6]^-}\] is the basis for the formation of first xenon compound. This is because ____________.
Which of the following compound is a peroxide?
These are physical properties of an elements.
- Sublimation enthalpy
- Ionisation enthalpy
- Hydration enthalpy
- Electron gain enthalpy
The total number of above properties that affect the reduction potential is ______. (Integer answer)
______ is a radioactive element in group 16 elements.
Given below are two statements:
Statement I: The boiling point of hydrides of Group 16 elements follows the order:
H2O > H2Te > H2Se > H2S
Statement II: On the basis of molecular mass, H2O is expected to have a lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has a higher boiling point.
In the light of the above statements, choose the correct answer from the options given below:
