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Question
Give one chemical test as an evidence to show that [Co (NH3)5Cl] are ionisation isomers.
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Solution
The ionisation isomers dissolve in water to yield different ions and thus react differently to various reagents.
[Co (NH3)5] SO4 ] Cl + Ba2+ → No reactions
[Co (NH3)5Cl]SO4 + Ag+ → No reactions
[Co (NH3)5SO4]Cl + Ag+ → AgCl (s) (white solid)
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Match List-I with List-II:
| List-I (Complex) |
List-II (Type of isomerism) |
| A. [Co(NH3)5(NO2)]Cl2 | I. Solvate isomerism |
| B. [Co(NH3)5(SO4)]Br | II. Linkage isomerism |
| C. [Co(NH3)6][Cr(CN)6] | III. Ionisation isomerism |
| D. [Co(H2O)6]Cl3 | IV. Coordination isomerism |
Choose the correct answer from the options given below:
