Advertisements
Advertisements
Question
Give one chemical test as an evidence to show that [Co (NH3)5Cl] are ionisation isomers.
Advertisements
Solution
The ionisation isomers dissolve in water to yield different ions and thus react differently to various reagents.
[Co (NH3)5] SO4 ] Cl + Ba2+ → No reactions
[Co (NH3)5Cl]SO4 + Ag+ → No reactions
[Co (NH3)5SO4]Cl + Ag+ → AgCl (s) (white solid)
APPEARS IN
RELATED QUESTIONS
Out of 
and 
, which one is optically active and why ?
Draw optical isomers of [Co(en)3]3+.
Which of the following does not show optical isomerism?
Complex [COCl2(en)2]+ can
Define Distereoisomers.
Write structures for geometrical isomers of diamminebromochloroplatinum (II).
What are structural isomers?
Match the pairs in column I (pairs of isomers) and column II (types of isomers)
| Column I (Pairs of isomers) |
Column II (Types of isomers) |
| (A) [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O | (i) Ionization isomers |
| (B) [Co(en)2(NO2)2]+ and [Co(en)2(ONO2)]+ | (ii) Hydrate isomers |
| (C) [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] | (iii) Linkage isomers |
| (D) [Pt(NH3)4Cl2] Br2 and [Pt(NH3)4Br2]Cl2 | (iv) Coordination isomers |
The co-ordination number of Co3+ ion in the complex [Co(NH3)4Cl2]⊕ is ______.
Name the type of isomerism exhibited by the following pair of compound:
\[\ce{[Pt(NH3)4Cl2]Br2 and [Pt(NH3)4 Br2]Cl2}\]
