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Tamil Nadu Board of Secondary EducationHSC Science Class 12

For the cell reaction 2FeX(aq)3++2lX(aq)−⟶2FeX(aq)2++lX2X(aq) EXcell0 = at 298 K. The standard Gibbs energy (∆G°) of the cell reactions is:

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Question

For the cell reaction

\[\ce{2Fe^{3+}_{( aq)} + 2l^-_{( aq)} -> 2Fe^{2+}_{( aq)} + l2_{( aq)}}\]

\[\ce{E^0_{cell}}\] = at 298 K. The standard Gibbs energy (∆G°) of the cell reactions is:

Options

  • – 46.32 KJ mol−1

  • – 23.16 KJ mol−1

  • 46.32 KJ mol−1

  • 23.16 KJ mol−1

MCQ
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Solution

– 46.32 KJ mol−1

Explanation:

n = 2; \[\ce{E^0_{cell}}\] = 0.24 V; ∆G° = ?; F = 96500 C

∆G° = – nFE°

∆G°= – 2 × 96500 × 0.24

∆G° = – 46320 J mol−1

∆G° = – 46.32 KJ mol−1

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Thermodynamics of Cell Reactions
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Chapter 9: Electro Chemistry - Evaluation [Page 65]

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Samacheer Kalvi Chemistry - Volume 1 and 2 [English] Class 12 TN Board
Chapter 9 Electro Chemistry
Evaluation | Q 22. | Page 65

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