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Questions
Distinguish between lanthanoid and actinoids.
Mention the properties in which lanthanoids differ from actinoids.
How do lanthanoids differ from actinoids?
Give three properties in which they differ from lanthanoids.
Write two differences between lanthanoids and actinoids.
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Solution 1
| Sr. No. | Lanthanoids | Actinoids |
| 1. | Differentiating electron enter 4f orbitals. | Differentiating electron enters 5f orbitals. |
| 2. | Belong to the sixth period and form part of the third transition series. They constitute the first inner transition series. | Belong to the seventh period and form part of the fourth transition series. They constitute the second inner transition series. |
| 3. | Binding energy of 4f orbitals is higher. | Binding energy of 5f orbitals is lower. |
| 4. | Besides the +3 oxidation state, lanthanoids show +2 and + 4 oxidation states in few cases. | Besides the +3 oxidation state, actinoids show higher oxidation states such as +4, +5 and +7. |
| 5. | They show lesser tendency to form complexes. | They show greater tendency to form complexes. |
| 6. | Some of the lanthanoids are fairly coloured. | Most of the ions of actinoids are deeply coloured. Examples: U3+ (red), U4+ (green). |
| 7. | Only promethium is radioactive. | All the members of this series are radioactive. |
Solution 2
| S. No. | Lanthanoids | Actinoids |
| 1. | Lanthanoids exhibit a maximum oxidation state of +4, with the other oxidation states being +2 and +3. | Actinoids exhibit a maximum oxidation state of +7, with the remaining oxidation states being +2, +3, +4, +5, and +6. |
| 2. | It is easy to explain their paramagnetic properties. | It can be difficult to explain their paramagnetic properties. |
| 3. | Lanthanoids are not radioactive, except promethium. | All actinoids are radioactive. |
| 4. | Complex formation is difficult for lanthanoids, particularly with π-bonding ligands. They only combine with specific chelating ligands to create complexes. | Actinoids are far more likely to form complexes. Even when π-bonding ligands are present, they can still form complexes. |
| 5. | They do not form oxocations. | They form several oxocations. |
| 6. | Their compounds are less basic | Their compounds are more basic |
Notes
Students should refer to the answer according to their questions.
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RELATED QUESTIONS
How would you account for the following:
The chemistry of actinoids is more complicated as compared to lanthanoids.
Give a reason for the following:
Actinoids show irregularities in their electronic configurations.
How would you account for the following:
Actinoid contraction is greater than lanthanoid contraction.
Why do actinoids show a wide range of oxidation states?
Write on similarity between the chemistry of lanthanoids and actinoids.
Which is the last element in the series of the actinoids? Write the electronic configuration of this element. Comment on the possible oxidation state of this element.
Compare the chemistry of the actinoids with that of lanthanoids with reference to electronic configuration
Compare the chemistry of the actinoids with that of lanthanoids with reference to oxidation states
Compare the chemistry of the actinoids with that of lanthanoids with reference to chemical reactivity.
Write four points of distinction between Lanthanoids and Actinoids.
Write one similarity and one difference between the chemistry of lanthanoid and actinoid elements.
What is the position of actinoids in periodic table ?
How do you prepare:
Actinoid elements show wide range of oxidation states.
Give reasons for the following:
The chemistry of actinoids elements is not so smooth as that of the lanthanoids.
Choose the most correct option.
In which of the following series all the elements are radioactive in nature?
Manganese in the +2 oxidation state is more stable than +3 oxidation state where as iron is stable at +3 oxidation state than +2 oxidation state. Explain why?
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Identify the CORRECT statement.
The actinoid contraction is attributed to the ____________.
The number of unpaired f-electrons in ytterbium (Z = 70) is ____________.
The highest oxidation state in plutonium (At. no. = 94) is ______.
The electronic configuration of Ux+ ion is [Rn]. What is the value of x?
[At. No. of U = 92]
Which among the following actinoids exhibits highest oxidation state +7?
Which of the following properties is NOT of actinoids?
Which among the following elements is radioactive?
The inner transition metals of 5f series are known as ____________.
Maximum oxidation state exhibited by Chlorine is ______.
Which of the following oxidation state is common for all lanthanoids?
Which of the following actinoids show oxidation states upto +7?
(i) Am
(ii) Pu
(iii) U
(iv) Np
Assertion: Actinoids form relatively less stable complexes as compared to lanthanoids.
Reason: Actinoids can utilise their 5f orbitals along with 6d orbitals in bonding but lanthanoids do not use their 4f orbital for bonding.
What is actinoid contraction?
What are actinoids? Give their general electronic configuration.
