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Questions
Discuss the main points of similarity between lanthanoids and actinoids.
Give three properties in which actinoids resemble lanthanoids.
Write two similarities between lanthanoids and actinoids.
Long Answer
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Solution
Lanthanoids and actinoids share similar features due to their (n − 2) f-subshell filling and outer electronic structure. The primary commonalities are as follows.
- Lanthanoids and actinoids have the same main oxidation state of +3.
- Both involve the filling of (n − 2) f-orbitals.
- Both are very electropositive and extremely reactive.
- Both display a decrease in atomic and ionic size (lanthanoid contraction and actinoid contraction) when the atomic number increases.
- Both show magnetic properties.
- Lanthanoids and actinoids form soluble nitrates, sulphates, and perchlorates during +3 oxidation, but insoluble hydroxides, carbonates, and fluorides.
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Notes
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