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Question
Discuss briefly the similarities between beryllium and aluminium.
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Solution
Diagonal relationship: As observed in alkali metals, beryllium shows a diagonal relationship with aluminium.
Similarities between beryllium and aluminium:
- Beryllium and aluminium have the same electronegativity values.
- Their changes per unit area are closed.
- BeCl2 and AlCl3 forms dimeric structure. Both are soluble in organic solvents and are strong Lewis acids.
- Be(OH)2 and Al(OH)3 dissolves in excess alkali to give beryllate ion [Be(OH)4]2– and aluminate ion [Al(OH)4]–, respectively.
- Be and Al ions have a strong tendency to form complexes, e.g. BeF42– and AlF63–
- Both Be(OFI)2 and Al(OH)3 are amphoteric in nature.
- Carbide of Be – beryllium carbide (Be2C) and Al – aluminium carbide (Al4C3) give methane on hydrolysis.
- Both beryllium and aluminium are rendered passive by nitric acid.
RELATED QUESTIONS
Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?
Which one of the alkaline earth metal carbonates is thermally the most stable?
Which of the following has the highest hydration energy
Explain the important common features of Group 2 elements.
When sodium is dissolved in liquid ammonia, a solution of deep blue colour is obtained. The colour of the solution is due to ______.
Discuss the trend of the following:
Thermal stability of carbonates of Group 2 elements.
What is the structure of BeCl2 molecule in gaseous and solid state?
Assertion (A): Beryllium carbonate is kept in the atmosphere of carbon dioxide.
Reason (R): Beryllium carbonate is unstable and decomposes to give beryllium oxide and carbon dioxide.
Alkaline earth metals show ______.
Among the following alkaline earth metal halides, one which is covalent and soluble in organic solvents is ______.
