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प्रश्न
Discuss briefly the similarities between beryllium and aluminium.
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उत्तर
Diagonal relationship: As observed in alkali metals, beryllium shows a diagonal relationship with aluminium.
Similarities between beryllium and aluminium:
- Beryllium and aluminium have the same electronegativity values.
- Their changes per unit area are closed.
- BeCl2 and AlCl3 forms dimeric structure. Both are soluble in organic solvents and are strong Lewis acids.
- Be(OH)2 and Al(OH)3 dissolves in excess alkali to give beryllate ion [Be(OH)4]2– and aluminate ion [Al(OH)4]–, respectively.
- Be and Al ions have a strong tendency to form complexes, e.g. BeF42– and AlF63–
- Both Be(OFI)2 and Al(OH)3 are amphoteric in nature.
- Carbide of Be – beryllium carbide (Be2C) and Al – aluminium carbide (Al4C3) give methane on hydrolysis.
- Both beryllium and aluminium are rendered passive by nitric acid.
संबंधित प्रश्न
Discuss the general characteristics and gradation in properties of alkaline earth metals.
The product obtained as a result of a reaction of nitrogen with CaC2 is ______.
Beryllium halides are covalent whereas magnesium halides are ionic why?
Name an element from Group 2 which forms an amphoteric oxide and a water soluble sulphate.
Discuss the trend of the following:
The solubility and the nature of oxides of Group 2 elements.
Why are BeSO4 and MgSO4 readily soluble in water while CaSO4, SrSO4 and BaSO4 are insoluble?
Assertion (A): Beryllium carbonate is kept in the atmosphere of carbon dioxide.
Reason (R): Beryllium carbonate is unstable and decomposes to give beryllium oxide and carbon dioxide.
An element of group 2 forms covalent oxide which is amphoteric in nature and dissolves in water to give an amphoteric hydroxide. Identify the element and write chemical reactions of the hydroxide of the element with an alkali and an acid.
Among the following alkaline earth metal halides, one which is covalent and soluble in organic solvents is ______.
PbCl4 exists but PbBr4 and Pbl4 do not because of ______.
