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प्रश्न
Discuss briefly the similarities between beryllium and aluminium.
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उत्तर
Diagonal relationship: As observed in alkali metals, beryllium shows a diagonal relationship with aluminium.
Similarities between beryllium and aluminium:
- Beryllium and aluminium have the same electronegativity values.
- Their changes per unit area are closed.
- BeCl2 and AlCl3 forms dimeric structure. Both are soluble in organic solvents and are strong Lewis acids.
- Be(OH)2 and Al(OH)3 dissolves in excess alkali to give beryllate ion [Be(OH)4]2– and aluminate ion [Al(OH)4]–, respectively.
- Be and Al ions have a strong tendency to form complexes, e.g. BeF42– and AlF63–
- Both Be(OFI)2 and Al(OH)3 are amphoteric in nature.
- Carbide of Be – beryllium carbide (Be2C) and Al – aluminium carbide (Al4C3) give methane on hydrolysis.
- Both beryllium and aluminium are rendered passive by nitric acid.
संबंधित प्रश्न
Discuss the general characteristics and gradation in properties of alkaline earth metals.
Which one of the alkaline earth metal carbonates is thermally the most stable?
The product obtained as a result of a reaction of nitrogen with CaC2 is ______.
Assertion: Generally alkali and alkaline earth metals form superoxides.
Reason: There is a single bond between O and O in superoxides.
Write a balanced chemical equation for the following chemical reaction.
Rubidium with oxygen gas
Beryllium halides are covalent whereas magnesium halides are ionic why?
Some of the Group 2 metal halides are covalent and soluble in organic solvents. Among the following metal halides, the one which is soluble in ethanol is ______.
What is the structure of BeCl2 molecule in gaseous and solid state?
Alkaline earth metals show ______.
Among the following alkaline earth metal halides, one which is covalent and soluble in organic solvents is ______.
