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प्रश्न
What is the structure of BeCl2 molecule in gaseous and solid state?
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उत्तर
Beryllium chloride has different structures in solid and vapour state. In solid-state, it exists in the form of polymeric chain structure in which each Be– atom is surrounded by four chlorine atoms, having two of the chlorine atoms covalently boned while the other two by coordinate bonds. The resulting bridge structure contains infinite chains.
Structure of BeCl2 in solid-state
In vapour state, above 1200 K, it exists as a monomer having linear structure and zero dipole moment. But below 1200 K, it exists as dimer even in the vapour state.
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संबंधित प्रश्न
Discuss the general characteristics and gradation in properties of alkaline earth metals.
Beryllium and magnesium do not give colour to flame whereas other alkaline earth metals do so. Why?
Which one of the alkaline earth metal carbonates is thermally the most stable?
The product obtained as a result of a reaction of nitrogen with CaC2 is ______.
Assertion: Generally alkali and alkaline earth metals form superoxides.
Reason: There is a single bond between O and O in superoxides.
Assertion: BeSO4 is soluble in water while BaSO4 is not
Reason: Hydration energy decreases down the group from Be to Ba and lattice energy remains almost constant.
Beryllium halides are covalent whereas magnesium halides are ionic why?
The reducing power of a metal depends on various factors. Suggest the factor which makes Li, the strongest reducing agent in aqueous solution.
Some of the Group 2 metal halides are covalent and soluble in organic solvents. Among the following metal halides, the one which is soluble in ethanol is ______.
Identify the correct formula of halides of alkaline earth metals from the following.
(i) BaCl2.2H2O
(ii) BaCl2.4H2O
(iii) CaCl2.6H2O
(iv) SrCl2.4H2O
Name an element from Group 2 which forms an amphoteric oxide and a water soluble sulphate.
Discuss the trend of the following:
Thermal stability of carbonates of Group 2 elements.
Why are BeSO4 and MgSO4 readily soluble in water while CaSO4, SrSO4 and BaSO4 are insoluble?
Assertion (A): Beryllium carbonate is kept in the atmosphere of carbon dioxide.
Reason (R): Beryllium carbonate is unstable and decomposes to give beryllium oxide and carbon dioxide.
An element of group 2 forms covalent oxide which is amphoteric in nature and dissolves in water to give an amphoteric hydroxide. Identify the element and write chemical reactions of the hydroxide of the element with an alkali and an acid.
Among the following alkaline earth metal halides, one which is covalent and soluble in organic solvents is ______.
Among the following alkaline earth metal halides, one which is covalent and soluble in organic solvents is ______.
Given below are two statements:
Statement I: Colourless cupric metaborate is reduced to cuprous metaborate in a luminous flame.
Statement II: Cuprous metaborate is obtained by heating boric anhydride and copper sulphate in a non-luminous flame.
In the light of the above statements, choose the most appropriate answer from the options given below.
