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Question
Describe a method to determine the specific heat capacity of a solid (say, a piece of copper).
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Solution
First we weigh the given piece of solid and note its mass m1. Then it is heated by suspending it inside a heater. Then a known mass (say m2) of water is taken in a thin glass beaker and its temperature θ1 is recorded with a thermometer. When the given piece of solid becomes heated, its temperature θ2 is noted and it is quickly dropped into the water contained in the beaker, such that no water splashes out. The contents of beaker are well stirred and the final highest temperature θ3 is noted.
Assuming that the heat capacity of beaker is negligible and there is not heat loss to the surroundings,
Heat lost by the solid = Heat gained by water Mass of solid × Specific heat capacity of solid × Fall in temperature of solid = Mass of water × Sp. capacity of water × Rise in temperature of water.
or m1 × c × (θ2 - θ3) = m3 × 4.2 × (θ3 - θ1)
or c = `("m"_2 xx 4.2 xx (theta_3 - theta_1))/(theta_1 xx (theta_2 - theta_3))` J/g°C
Here we have assumed that specific heat capacity of water is 4.2 J/g°C.
RELATED QUESTIONS
Given below are observations on molar specific heats at room temperature of some common gases.
| Gas |
Molar specific heat (Cv) (cal mol–1 K–1) |
| Hydrogen | 4.87 |
| Nitrogen | 4.97 |
| Oxygen | 5.02 |
| Nitric oxide | 4.99 |
| Carbon monoxide | 5.01 |
| Chlorine | 6.17 |
The measured molar specific heats of these gases are markedly different from those for monatomic gases. Typically, molar specific heat of a monatomic gas is 2.92 cal/mol K. Explain this difference. What can you infer from the somewhat larger (than the rest) value for chlorine?
Water property of water makes it an effective coolant?
Name the radiations for which the green house gases are opaque ?
The specific heat capacity of a body depends on _____________ .
If 10125 J of heat energy boils off 4.5 g of water at 100°C to steam at 100°C, find the specific latent heat of steam.
What are other units of heat? Name and define them.
State the condition for the flow of heat energy from one body to another.
The molar specific heat of a gas at constant volume is 12307.69 J kg-1 K-1. If the ratio of the two specific heats is 1.65, calculate the difference between the two molar specific heats of gas.
Derive Mayer’s relation.
If 'f' is the number of degrees of freedom of a molecule of a gas and ratio of molar specific heats of a gas, ϒ = 1 + `2/"f"` where ϒ = Cp/Cv. The ratio of 'ϒ' for monoatomic gas to 'ϒ' for (rigid) f diatomic gas is ______.
