English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Consider the figure and answer the following question.Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode - Chemistry

Advertisements
Advertisements

Question

Consider the figure and answer the following question.

Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode reactions will occur in this cell?

Long Answer
Advertisements

Solution

Cell ‘B’ will act as electrolytic cell as it has lower emf

∴ The electrode reactions will be:

\[\ce{Zn^{2+} + 2e^{-} -> Zn}\] at cathode

\[\ce{Cu -> Cu^{2+} + 2e^{-}}\] at anode

shaalaa.com
  Is there an error in this question or solution?
Chapter 3: Electrochemistry - Exercises [Page 43]

APPEARS IN

NCERT Exemplar Chemistry [English] Class 12
Chapter 3 Electrochemistry
Exercises | Q VI. 66. (i) | Page 43

RELATED QUESTIONS

The charge of how many coulomb is required to deposit 1.0 g of sodium metal (molar mass 23.0 g mol-1) from sodium ions is -

  1. 2098
  2. 96500
  3. 193000
  4. 4196

96500 coulombs correspond to the charge on how many electrons?


Following reactions occur at cathode during the electrolysis of aqueous sodium chloride solution:

Na+(aq) + e ⟶ Na (s) E0 =  2.71 V

H+(aq) + e ⟶ `1/2`  H2 (g) E0 = 0.00 V

On the basis of their standard reduction electrode potential (E0) values, which reaction is feasible at the cathode and why?


If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?


How much charge is required for the following reduction:

1 mol of \[\ce{MnO^-_4}\] to Mn2+?


Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?


Write any two uses of H2SO4


Draw neat labelled diagram of electrolytic refining of blister copper


Write the name of the cell which is generally used in transistors. Write the reactions taking place at the anode and the cathode of this cell.


 Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :

On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?


What will happen during the electrolysis of aqueous solution of CuSO4 in the presence of Cu electrodes?

(i) Copper will deposit at cathode.

(ii) Copper will dissolve at anode.

(iii) Oxygen will be released at anode.

(iv) Copper will deposit at anode.


Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.

Reason: Formation of oxygen at anode requires overvoltage.


Time Required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through aqueous solution of aluminium is


On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be ______.


The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.


What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).


Through an aqueous solution of an unknown salt of metal M (M = 200 g/mol) a current of 1.93 A is passed for 50 min. If 4 g of metal is produced at cathode. The charge on metal ion in solution is ______.


How much electricity in terms of Faraday is required to produce 40.0 g of Al from molten Al2O3?

(Given: Molar mass of Aluminium is 27 g mol−1.)


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×