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Question
An ideal monoatomic gas is adiabatically compressed so that its final temperature is twice its initial temperature. What is the ratio of the final pressure to its initial pressure?
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Solution 1
Data: Tf = 2Ti, monoatomic gas ∴ ϒ = 5/3
PiViϒ = PfVfϒ in an adiabatic process
Now, PV = ηRT ∴ V = `(η"RT")/"P"`
∴ Vi = `(η"RT"_"i")/"P"_"i"` and Vf = `(η"RT"_"f")/"P"_"f"`
∴ Pi `((η"RT")/"P"_"i")^ϒ="P"_"f"((η"RT"_"f")/"P"_"f")^ϒ`
∴ `"P"_"i"^(1-ϒ)"T"_"i"^ϒ="P"_"f"^(1-ϒ)"T"_"f"^ϒ`
∴ `(("T"_"f")/"T"_"i")^ϒ=(("P"_"i")/("P"_"f"))^(1-ϒ)`
∴ `(("T"_"f")/"T"_"i")^ϒ=(("P"_"f")/("P"_"i"))^(ϒ-1)`
∴ 25/3 = `(("P"_"f")/("P"_"i"))^(5//3-1)=(("P"_"f")/("P"_"i"))^(2//3)`
∴ `5/3` log 2 = `2/3` log `"P"_"f"/"p"_"i"`
∴ `5/3xx0.3010 = 2/3` log `(("P"_"f")/"P"_"i")`
∴ (2.5) (0.3010) = log `(("P"_"f")/("P"_"i"))`
∴ 0.7525 = log `("P"_"f"/"P"_"i")`
∴ `("P"_"f")/"P"_"i"` = antilog 0.7525 = 5.656
This is the ratio of the final pressure (Pf) to the initial pressure (Pi).
Solution 2
Given: Tf = 2Ti, `"P"_"f"/"P"_"i"` = ?
Formula:
`"P"_"f"/"P"_"i" = (("T"_"f")/("T"_"i"))^(gamma/(gamma - 1))`
∴ `"P"_"f"/"P"_"i" = ((2"T"_"i")/("T"_"i"))^((5"/"3)/(5"/"3 - 1))` ............`(∵ "For mono-atomic gas", gamma = 5/3)`
∴ `"P"_"f"/"P"_"i" = 2^2.5`
∴ `"P"_"f"/"P"_"i" = 5.6568`
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