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What are chemical twins? Write ‘two’ examples.
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A reaction is second order in A and first order in B.
(i) Write the differential rate equation.
(ii) How is the rate affected on increasing the concentration of A three times?
(iii) How is the rate affected when the concentrations of both A and B are doubled?
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Distinguish between crystalline solid and amorphous solid.
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What is pseudo first order reaction? Give one· example of it.
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which of the following carbocations is least stable?
(A) 
(B)![]()
(C)![]()
(D)
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Compound having general formula
is called
(A) diester
(B) acid anhydride
(C) hemiacetal
(D) acetal
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Write the fomulae of the following compounds
Sodium hexanitrito- N - cobaltate (III)
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Write molecularity of the following reaction:
2NO(g)+O2(g)→2NO2(g)
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Describe anomalous behaviour of fluorine with the other elements of group 17 wilh reference to :
(a) Hydrogen bonding
(b) Oxidation state
(c) Polyhalide ions
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Which among the following pairs of elements is 'not' an example of chemical twins?
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For a reaction: 
Rate = k
(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k.
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Write two differences between an ideal solution and a non-ideal solution.
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Write two factors that affect the rate of reaction.
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For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
How is the rate of reaction affected if the concentration of B is doubled?
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For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
What is the overall order of reaction if A is present in large excess?
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For a reaction : 
(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k.
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Account for the following : Nitrogen does not form pentahalide.
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For the hydrolysis of methyl acetate in aqueous solution, the following results were obtained :
| t/s | 0 | 30 | 60 |
| [CH3COOCH3] / mol L–1 | 0.60 | 0.30 | 0.15 |
(i) Show that it follows pseudo first order reaction, as the concentration of water remains constant.
(ii) Calculate the average rate of reaction between the time interval 30 to 60 seconds.
(Given log 2 = 0.3010, log 4 = 0.6021)
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The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume :
SO2Cl2 (g) → SO2 (g) + Cl2 (g)
| Experiment | Time/s–1 | Total pressure/atm |
| 1 | 0 | 0.4 |
| 2 | 100 | 0.7 |
Calculate the rate constant.
(Given : log 4 = 0.6021, log 2 = 0.3010)
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