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Science (English Medium) इयत्ता १२ - CBSE Question Bank Solutions for Chemistry

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Chemistry
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\[\ce{KMnO4}\] acts as an oxidising agent in acidic medium. The number of moles of \[\ce{KMnO4}\] that will be needed to react with one mole of sulphide ions in acidic solution is ______.

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals. Which of the following is not the characteristic property of interstitial compounds?

[4] d-block and f-block Elements
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The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of Cr3+ ion is ______.

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Which of the following statements is not correct?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.

[4] d-block and f-block Elements
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Highest oxidation state of manganese in fluoride is \[\ce{+4 (MnF4)}\] but highest oxidation state in oxides is \[\ce{+7 (Mn2O7)}\] because ______.

[4] d-block and f-block Elements
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Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they show similar physical and chemical properties because ______.

[4] d-block and f-block Elements
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Why is \[\ce{HCl}\] not used to make the medium acidic in oxidation reactions of \[\ce{KMnO4}\] in acidic medium?

[4] d-block and f-block Elements
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Transition elements show magnetic moment due to spin and orbital motion of electrons. Which of the following metallic ions have almost same spin only magnetic moment?

(i) \[\ce{Co^{2+}}\]

(ii) \[\ce{Cr^{2+}}\]

(iii) \[\ce{Mn^{2+}}\]

(iv) \[\ce{Cr^{3+}}\]

[4] d-block and f-block Elements
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Which of the following ions show higher spin only magnetic moment value?

(i) \[\ce{Ti^3+}\]

(ii) \[\ce{Mn2+}\]

(iii) \[\ce{Fe2+}\]

(iv) \[\ce{Co3+}\]

[4] d-block and f-block Elements
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Transition elements form binary compounds with halogens. Which of the following elements will form \[\ce{MF3}\] type compounds?

(i) \[\ce{Cr}\]

(ii) \[\ce{Co}\]

(iii) \[\ce{Cu}\]

(iv) \[\ce{Ni}\]

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Which of the following will not act as oxidising agents?

(i) \[\ce{CrO3}\]

(ii) \[\ce{MoO3}\]

(iii) \[\ce{WO3}\]

(iv) \[\ce{CrO^{2-}4}\]

[4] d-block and f-block Elements
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Why does copper not replace hydrogen from acids?

[4] d-block and f-block Elements
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Why EΘ values for Mn, Ni and Zn are more negative than expected?

[4] d-block and f-block Elements
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Transition elements show high melting points. Why?

[4] d-block and f-block Elements
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Out of \[\ce{Cu2Cl2}\] and \[\ce{CuCl2}\], which is more stable and why?

[4] d-block and f-block Elements
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When a brown compound of manganese (A) is treated with \[\ce{HCl}\] it gives a gas (B). The gas taken in excess, reacts with \[\ce{NH3}\] to give an explosive compound (C). Identify compounds A, B and C.

[4] d-block and f-block Elements
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Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilise higher oxidation states exceeds that of fluorine. Why?

[4] d-block and f-block Elements
Chapter: [4] d-block and f-block Elements
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Although \[\ce{Cr^3+}\] and \[\ce{Co^2+}\] ions have same number of unpaired electrons but the magnetic moment of \[\ce{Cr^3+}\] is 3.87 B.M. and that of \[\ce{Co^2+}\] is 4.87 B.M. Why?

[4] d-block and f-block Elements
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Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. Why?

[4] d-block and f-block Elements
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