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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write Chemical Reactions for Different Steps in the Manufacture of Sulphuric Acid by Lead Chamber Process. Draw the Structure of Phosphorous Pentachloride

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प्रश्न

Write chemical reactions for different steps in the manufacture of sulphuric acid by lead chamber process. Draw the structure of phosphorous pentachloride

थोडक्यात उत्तर
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उत्तर

2SO2 + O2 +2H2O`overset("No"  )(->)`2H2SO4 

The above net reaction can be written as the sum of the following reactions taking place in different steps.
1) 2H2O +NO `rightarrow` HNO3 +3H+

2) S + O2 `rightarrow` SO2 (Oxidation of sulphur)

3) 2HNO3 + 2SO2 `rightarrow` H2O +NO +NO2 +2SO3

Nitric acid or NO2 is used to oxidize SO2 to SO3.

Or   SO2 +NO2 `rightarrow` SO3 + NO

4) SO3 +H2O `rightarrow` H2SO4

Sulphur trioxide reacts with water to form  H2SO4 .

Structure of phosphorous pentachloride :

Phosphorous has 5 valence electrons. Each electron is shared with a chlorine atom.

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2018-2019 (March) Set 1

संबंधित प्रश्‍न

What is molecular formula of oleum?

(a) H2SO3

(b) H2SO4

(c) H2S2O7

(d) H2S2O8


Write the conditions to maximize the yield of H2SO4 by contact process.


Complete the following equations:

\[\ce{C + conc{.} H2SO4 ->}\]


Draw the structure of the following:

H2SO4


Describe the manufacture of H2SO4 by contact process?


Write balanced equations for NaCl is heated with sulphuric acid in the presence of MnO2


What is the action of concentrated sulphuric acid on phosphorous pentachloride


What happens when dilute sulphuric acid is treated with Fe


What happens when dilute sulphuric acid is treated with CaF2


What is the action of concentrated sulphuric acid on potassium chlorate?


Give balanced chemical equations for Sulphuric acid is treated with hydrogen sulphide


 Complete and balance the following equations: 
S+H2SO4(conc.)  → 


Write structure and molecular formula for the following compounds:
a. Orthophosphoric acid 
b. Sulphurous acid


Write the formula for pentaamminechlorocobalt (III) sulphate. 


Which of the following reaction is NOT involved in contact process used for manufacturing sulfuric acid?


Identify the INCORRECT statement about H2SO4.


The molecular formula of oleum is ____________.


Which among the following catalysts is used in manufacture of sulphuric acid by contact process?


What is the ratio of volumes of gases involved in the preparation of sulphur trioxide from sulphur dioxide and dioxygen respectively under similar conditions of temperature and pressure?


Hot conc. \[\ce{H2SO4}\] acts as the moderately strong oxidising agent. It oxidises both metals and non-metals. Which of the following element is oxidised by conc. \[\ce{H2SO4}\] into two gaseous products?


The number of dative bonds in sulphric acid molecule is ______.


Write the reaction of conc. H2SO4 with sugar. What is the role of H2SO4 in this reaction?


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