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प्रश्न
What is the action of concentrated sulphuric acid on phosphorous pentachloride
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उत्तर
Concentrated sulphuric acid reacts with PCl5 to form chlorosulphuric acid.
`HOSO_2OH + PCl_5 -> ClSO_2OH + POCl_3 +HCl`
Sulphuric acid Phosphorus Chlorosulphuric acid
pentachloride
Chlorosulphuric acid further reacts with PCl5 to form sulphuryl chloride.
`ClSO_2OH + PCl_5 -> ClSO_2Cl + POCl_3 + HCL`
Chlorosulphuric Phosphorus Sulphuryl
acid pentachloride chloride
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संबंधित प्रश्न
Write the conditions to maximize the yield of H2SO4 by contact process.
Complete the following equations: C + conc. H2SO4 →
Draw the structure of the following:
H2SO4
Mention three areas in which H2SO4 plays an important role.
Write balanced equations for NaCl is heated with sulphuric acid in the presence of MnO2
What is the action of concentrated sulphuric acid on copper
When concentrated sulphuric acid was added to an unknown salt present in a test tube a brown gas (A) was evolved. This gas intensified when copper turnings were added to this test tube. On cooling, the gas (A) changed into a colourless solid (B).
1) Identify (A) and (B).
2) Write the structures of (A) and (B).
3) Why does gas (A) change to solid on cooling?
Write chemical reactions for different steps in the manufacture of sulphuric acid by lead chamber process. Draw the structure of phosphorous pentachloride
Complete and balance the following equations:
S+H2SO4(conc.) →
Write a balanced chemical equation for the following reaction:
Sulphuric acid is treated with phosphorous.
Write the formula for pentaamminechlorocobalt (III) sulphate.
Which of the following reaction is NOT involved in contact process used for manufacturing sulfuric acid?
Identify the INCORRECT statement about H2SO4.
Identify the products formed when conc. sulfuric acid reacts with calcium fluoride.
Gas 'X' is prepared by treating sodium sulfite with dilute sulfuric acid. When gas 'X' is oxidised by dioxygen in presence of vanadium (V) oxide, gas 'Y' is formed. Identify X and Y.
The molecular formula of oleum is ____________.
Which among the following catalysts is used in manufacture of sulphuric acid by contact process?
Hot conc. \[\ce{H2SO4}\] acts as the moderately strong oxidising agent. It oxidises both metals and non-metals. Which of the following element is oxidised by conc. \[\ce{H2SO4}\] into two gaseous products?
Which of the following statements are correct?
(i) S – S bond is present in \[\ce{H2S2O6}\].
(ii) In peroxosulphuric acid \[\ce{(H2SO5)}\] sulphur is in +6 oxidation state.
(iii) Iron powder along with \[\ce{Al2O3}\] and \[\ce{K2O}\] is used as a catalyst in the preparation of \[\ce{NH3}\] by Haber’s process.
(iv) Change in enthalpy is positive for the preparation of \[\ce{SO3}\] by catalytic oxidation of \[\ce{SO2}\].
The oxidation number of sulphur in Na2S4O6 is:-
The number of dative bonds in sulphric acid molecule is ______.
