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प्रश्न
Write chemical reactions for different steps in the manufacture of sulphuric acid by lead chamber process. Draw the structure of phosphorous pentachloride
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उत्तर
2SO2 + O2 +2H2O`overset("No" )(->)`2H2SO4
The above net reaction can be written as the sum of the following reactions taking place in different steps.
1) 2H2O +NO `rightarrow` HNO3 +3H+
2) S + O2 `rightarrow` SO2 (Oxidation of sulphur)
3) 2HNO3 + 2SO2 `rightarrow` H2O +NO +NO2 +2SO3
Nitric acid or NO2 is used to oxidize SO2 to SO3.
Or SO2 +NO2 `rightarrow` SO3 + NO
4) SO3 +H2O `rightarrow` H2SO4
Sulphur trioxide reacts with water to form H2SO4 .
Structure of phosphorous pentachloride :
Phosphorous has 5 valence electrons. Each electron is shared with a chlorine atom.
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संबंधित प्रश्न
Write the conditions to maximize the yield of H2SO4 by contact process.
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Complete the following equations: C + conc. H2SO4 →
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H2SO4
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Why is `K_(a_2) "<<" K_(a_1)` for `H_2SO_4` in water?
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Complete and balance the following equations:
S+H2SO4(conc.) →
Write a balanced chemical equation for the following reaction:
Sulphuric acid is treated with phosphorous.
Write structure and molecular formula for the following compounds:
a. Orthophosphoric acid
b. Sulphurous acid
Write the formula for pentaamminechlorocobalt (III) sulphate.
Identify the INCORRECT statement about H2SO4.
Identify the products formed when conc. sulfuric acid reacts with calcium fluoride.
Gas 'X' is prepared by treating sodium sulfite with dilute sulfuric acid. When gas 'X' is oxidised by dioxygen in presence of vanadium (V) oxide, gas 'Y' is formed. Identify X and Y.
The molecular formula of oleum is ____________.
The sulfuric acid obtained by contact process is ____________ % pure.
Hot conc. \[\ce{H2SO4}\] acts as the moderately strong oxidising agent. It oxidises both metals and non-metals. Which of the following element is oxidised by conc. \[\ce{H2SO4}\] into two gaseous products?
Which of the following statements are correct?
(i) S – S bond is present in \[\ce{H2S2O6}\].
(ii) In peroxosulphuric acid \[\ce{(H2SO5)}\] sulphur is in +6 oxidation state.
(iii) Iron powder along with \[\ce{Al2O3}\] and \[\ce{K2O}\] is used as a catalyst in the preparation of \[\ce{NH3}\] by Haber’s process.
(iv) Change in enthalpy is positive for the preparation of \[\ce{SO3}\] by catalytic oxidation of \[\ce{SO2}\].
The number of dative bonds in sulphric acid molecule is ______.
What is the catalyst used for the oxidation of SO2 to SO3 in the lead chamber process for the manufacture of sulphuric acid?
Write the reaction of conc. H2SO4 with sugar. What is the role of H2SO4 in this reaction?
