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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write Balanced Chemical Equations for the Conversion of Cro_4^(2-) to Cr_2o_7^(2-) in Acidic Medium and Cr_2o_7^(2-) to Cro_4^(2-) In Basic Medium - Chemistry

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प्रश्न

Write balanced chemical equations for the conversion of `CrO_4^(2-)` to `Cr_2O_7^(2-)` in acidic medium and `Cr_2O_7^(2-)` to `CrO_4^(2-)`
 in basic medium.

थोडक्यात उत्तर
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उत्तर

`K_2Cr_2O_7 + 2KOH -> 2K_2CrO_4 + H_2O`

`2K_2CrO_4 + 2HCl -> K_2Cr_2O_7 + 2KCl + H_2O`

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
2017-2018 (March)

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संबंधित प्रश्‍न

Explain why is Fe3+ more stable than Fe2+?


ln which pair highest oxidation states of transition metals are found:


Why do the transition elements have higher enthalpies of atomisation?


In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization of zinc is the lowest, i.e., 126 kJ mol−1. Why?


What may be the stable oxidation state of the transition element with the following d electron configurations in the ground state of its atom?

3d3


How would you account for the following: 

The d1 configuration is very unstable in ions.


What are alloys?


Which one of the following ions is coloured?


An analysis shows that FeO has a non-stoichiometric composition with formula Fe0.95O. Give reason.


The paramagnetic character in the 3d-transition series elements increases up to Mn and then decreases.


Account for the following : 
 Ti4+ is colourless whereas V4+  is coloured in an aqueous solutions. 


Explain why Mn2+ is more stable than Fe2+ towards oxidation to +3 state. (At. no. of Mn = 25, Fe = 26)


Give reasons for the following:

The transition metals generally form coloured compounds.


Which among the following transition metal has the lowest melting point?


Maximum oxidation state is shown by ____________.


Why EΘ values for Mn, Ni and Zn are more negative than expected?


When a brown compound of manganese (A) is treated with \[\ce{HCl}\] it gives a gas (B). The gas taken in excess, reacts with \[\ce{NH3}\] to give an explosive compound (C). Identify compounds A, B and C.


Answer the following question:

Which element of the first transition series has highest third ionisation enthalpy?


If enthalpies of formation of C2H4(g), CO2(g) and H2O(l) at 25°C and 1 atm pressure are 52, – 394 and – 286 kJ/mol respectively, the change in ethalpy for combustion of C2H4 is equal to


The orientation of an atomic orbital is governed by


Photographic film and plates have - au essential ingredient of


Sodium this sulphate is used in photography because of its:-


Which one of the following characters tie of the transition metal is associated with higher catalytic activity?


Consider the following standard electrode potential values:

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = +0.77 V

\[\ce{MnO^{-4}_{ (aq)} + 8H^+ + 5e^- -> Mn^{2+}_{ (aq)} + 4H2O_{(l)}}\], E0 = +1.51 V

What is the cell potential for the redox reaction?


The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.


Give two similarities in the properties of Sc and Zn.


Explain the use of different transition metals as catalysts.


A coordination compound has the formula \[\ce{CoCl3.4NH3}\]. It precipitates silver ions as AgCl and its molar conductance corresponds to a total of two ions.

Based on this information, answer the following question:

  1. Deduce the structural formula of the complex compound.
  2. Write the IUPAC name of the complex compound.
  3. Draw the geometrical isomers of the complex compound.

Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Atomic sizes


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