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प्रश्न
Assertion (A): Cu cannot liberate hydrogen from acids.
Reason (R): Because it has positive electrode potential.
Assertion (A): Cu cannot liberate H2 on reaction with dilute mineral acids.
Reason (R): Cu has positive electrode potential.
पर्याय
Both assertion and reason are true, and reason is the correct explanation of the assertion.
Both assertion and reason are true but reason is not the correct explanation of assertion.
Assertion is not true but reason is true.
Both assertion and reason are false.
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उत्तर
Both assertion and reason are true, and reason is the correct explanation of the assertion.
Explanation:
Copper has a positive electrode potential, so it is less reactive than hydrogen and cannot displace H+ ions from dilute acids to release hydrogen gas.
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संबंधित प्रश्न
Why is Sc3+ colourless while Ti3+ coloured? (Atomic number Sc = 21, Ti =22)
Explain why is Fe3+ more stable than Fe2+?
Account for the following:
Cu+2 salts are coloured, while Zn2+ salts are white.
How would you account for the following : Transition metals form coloured compounds
How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.
For M2+/M and M3+/M2+ systems, the E° values for some metals are as follows:
| Cr2+/Cr | −0.9 V |
| Mn2+/Mn | −1.2 V |
| Fe2+/Fe | −0.4 V |
| Cr3/Cr2+ | −0.4 V |
| Mn3+/Mn2+ | +1.5 V |
| Fe3+/Fe2+ | +0.8 V |
Use this data to comment upon:
- The stability of Fe3+ in acid solution as compared to that of Cr3+ or Mn3+ and
- the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.
Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.
Two metallic elements A and B have the following standard oxidation potentials: A = 0·40v B = - 0·80v. What would you expect if element A was added to an aqueous salt solution of element B? Give a reason for your answer.
Which among the following transition metal has the lowest melting point?
The magnetic nature of elements depends on the presence of unpaired electrons. Identify the configuration of transition element, which shows highest magnetic moment.
Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals. Which of the following is not the characteristic property of interstitial compounds?
Transition elements form binary compounds with halogens. Which of the following elements will form \[\ce{MF3}\] type compounds?
(i) \[\ce{Cr}\]
(ii) \[\ce{Co}\]
(iii) \[\ce{Cu}\]
(iv) \[\ce{Ni}\]
Why does copper not replace hydrogen from acids?
When a brown compound of manganese (A) is treated with \[\ce{HCl}\] it gives a gas (B). The gas taken in excess, reacts with \[\ce{NH3}\] to give an explosive compound (C). Identify compounds A, B and C.
Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilise higher oxidation states exceeds that of fluorine. Why?
Which of the following transition metal is not coloured?
Match List - I with List - II.
| List - I | List - II | ||
| (A) | [Fe(CN)6]3− | (i) | 5.92 BM |
| (B) | [Fe(H2O)6]3+ | (ii) | 0 BM |
| (C) | [Fe(CN)6]4− | (iii) | 4.90 BM |
| (D) | [Fe(H2O)6]2+ | (iv) | 1.73 BM |
Choose the correct answer from the options given below.
The disproportionation of \[\ce{MnO^{2-}_4}\] in acidic medium resulted in the formation of two manganese compounds A and B. If the oxidation state of Mn in B is smaller than that of A, then the spin-only magnetic moment (µ) value of B in BM is ______. (Nearest integer)
Why are interstitial compounds well known for transition metals?
Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iron (II) solution.
