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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Transition elements form binary compounds with halogens. Which of the following elements will form MFX3 type compounds? (i) Cr (ii) Co (iii) Cu (iv) Ni

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प्रश्न

Transition elements form binary compounds with halogens. Which of the following elements will form \[\ce{MF3}\] type compounds?

(i) \[\ce{Cr}\]

(ii) \[\ce{Co}\]

(iii) \[\ce{Cu}\]

(iv) \[\ce{Ni}\]

टीपा लिहा
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उत्तर

(i) \[\ce{Cr}\]

(ii) \[\ce{Co}\]

Explanation:

\[\ce{Cr}\] and \[\ce{Co}\] form \[\ce{MF3}\] type of compounds. The ability of fluorine to stabilize the highest oxidation state is due to higher lattice energy in \[\ce{CoF3}\] and higher bond enthalpy for the higher covalent compound like \[\ce{CrF6}\].

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११०]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 29 | पृष्ठ ११०

संबंधित प्रश्‍न

Account for the following: 

Cr2+ is a strong reducing agent.


How would you account for the following: Transition metals form complex compounds.


Which is a stronger reducing agent, Cr2+ or Fe2+ and why?


Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

1) Which ion is most stable in an aqueous solution and why?

2) Which ion is a strong oxidising agent and why?

3) Which ion is colourless and why?


An analysis shows that FeO has a non-stoichiometric composition with formula Fe0.95O. Give reason.


Complete and balance the following chemical equations

`Fe^(2+) + MnO_4^(-) + H^+ ->`


The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of Cr3+ ion is ______.


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Identify A to E and also explain the reactions involved.


When a chromite ore (A) is fused with sodium carbonate in free excess of air and the product is dissolved in water, a yellow solution of compound (B) is obtained. After treatment of this yellow solution with sulphuric acid, compound (C) can be crystallised from the solution. When compound (C) is treated with KCl, orange crystals of compound (D) crystallise out. Identify A to D and also explain the reactions.


Which of the following is non-metallic?


If enthalpies of formation of C2H4(g), CO2(g) and H2O(l) at 25°C and 1 atm pressure are 52, – 394 and – 286 kJ/mol respectively, the change in ethalpy for combustion of C2H4 is equal to


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Which of the following transition metals shows +1 and +2 oxidation states?


Account for the following:

Eu2+ with electronic configuration [Xe]4f76s2 is a strong reducing agent.


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For M2+/M and M3+/M2+systems, the EΘ values for some metals are as follows:

Cr2+/Cr −0.9 V
Mn2+/Mn −1.2 V
Fe2+/Fe −0.4 V
Cr3/Cr2+ −0.4 V
Mn3+/Mn2+ +1.5 V
Fe3+/Fe2+ +0.8 V

Use this data to comment upon:

The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.


Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Oxidation states


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