मराठी

What is Meant by Negative Deviation from Raoult'S Law? Give an Example. What is the Sign of ∆Mixh for Negative Deviation?

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प्रश्न

What is meant by negative deviation from Raoult's law? Give an example. What is the sign of ∆mixH for negative deviation?

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उत्तर

The non-ideal solutions that do not obey Raoult's law over the entire range of concentration and have vapour pressures lower than those predicted by Raoult's law show a negative deviation from Raoult's law.

Example: A mixture of chloroform and acetone

In case of solutions showing negative deviations, ΔmixH has a negative sign.

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2014-2015 (March) Foreign Set 2

संबंधित प्रश्‍न

Calculate the mass of a non-volatile solute (molar mass 40 g mol−1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.


A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate:

  1. molar mass of the solute.
  2. vapour pressure of water at 298 K.

Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene.


For the reaction :

\[\ce{2NO_{(g)} ⇌ N2_{(g)} + O2_{(g)}}\];

ΔH = -heat

K= 2.5 × 10at 298K

What will happen to the concentration of Nif :

(1) Temperature is decreased to 273 K.

(2) The pressure is reduced


At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is ______.


An aqueous solution of hydrochloric acid:


Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law?


On the basis of information given below mark the correct option.
On adding acetone to methanol some of the hydrogen bonds between methanol molecules break.


A solution of a non-volatile solute in water freezes at −0.30°C. The vapour pressure of pure water at 298 K is 23.51 mm Hg and Kf for water is 1.86 degree/mol. The vapour pressure of rain solution at 298 K is ______ mm Hg.


An azeotropic mixture of two liquids will have a boiling point lower than either of the two liquids when it ______.


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