मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Calculate the mass of a non-volatile solute (molar mass 40 g mol−1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%. - Chemistry

Advertisements
Advertisements

प्रश्न

Calculate the mass of a non-volatile solute (molar mass 40 g mol−1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.

संख्यात्मक
Advertisements

उत्तर

`(p^circ - p)/p^circ = (w M)/(W M')`

or `1 - p/p^circ = (w M)/(W M')`

By substituting the given values, we get

`1 - 80/100 = (w xx 114)/(114 xx 40)`    ...(Mol. mass of octane = 114)

or `20/100 = w/40`

or `w = (20 xx 40)/100`

w = 8 g

shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 1: Solutions - Exercises [पृष्ठ २८]

APPEARS IN

एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 1 Solutions
Exercises | Q 1.18 | पृष्ठ २८

संबंधित प्रश्‍न

In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes?


What is meant by positive deviations from Raoult's law? Give an example. What is the sign of ∆mixH for positive deviation?


Why does a solution containing non-volatile solute have higher boiling point than the pure solvent ?


What type of deviation is shown by a mixture of ethanol and acetone? Give reason.


Vapour pressure of pure water at 298 K is 23.8 mm Hg. 50 g of urea (NH2CONH2) is dissolved in 850 g of water. Calculate the vapour pressure of water for this solution and its relative lowering.


The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a non-volatile solute in it.


What type of azeotrope is formed by positive deviation from Raoult’s law?


Some liquids on mixing form 'azeotropes'. What are 'azeotropes'?


For the reaction :

\[\ce{2NO_{(g)} ⇌ N2_{(g)} + O2_{(g)}}\];

ΔH = -heat

K= 2.5 × 10at 298K

What will happen to the concentration of Nif :

(1) Temperature is decreased to 273 K.

(2) The pressure is reduced


A solution containing 8.44 g of sucrose in 100 g of water has a vapour pressure 4.56 mm of Hg at 273 K. If the vapour pressure of pure water is 4.58 mm of Hg at the same temperature, calculate the molecular weight of sucrose. 


Define Raoult’s law for the elevation of the boiling point of a solution.


What will be the vapour pressure of a solution containing 5 moles of sucrose (C12H22O11) in 1 kg of water, if the vapour pressure of pure water is 4.57 mm of Hg? [C = 12, H = 1, O = 16]


Raoult’s law states that for a solution of volatile liquids the partial pressure of each component in the solution is ____________.


At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is ______.


On the basis of information given below mark the correct option.

(A) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same as A–B type interactions.

(B) In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type interactions.

(C) In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type interactions.


Using Raoult’s law explain how the total vapour pressure over the solution is related to mole fraction of components in the following solutions.

\[\ce{CHCl3(l) and CH2Cl2(l)}\]


Two liquids X and Y form an ideal solution. The mixture has a vapour pressure of 400 mm at 300 K when mixed in the molar ratio of 1 : 1 and a vapour pressure of 350 mm when mixed in the molar ratio of 1 : 2 at the same temperature. The vapour pressures of the two pure liquids X and Y respectively are ______.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×