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What is Meant by Negative Deviation from Raoult'S Law? Give an Example. What is the Sign of ∆Mixh for Negative Deviation? - Chemistry

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प्रश्न

What is meant by negative deviation from Raoult's law? Give an example. What is the sign of ∆mixH for negative deviation?

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उत्तर

The non-ideal solutions that do not obey Raoult's law over the entire range of concentration and have vapour pressures lower than those predicted by Raoult's law show a negative deviation from Raoult's law.

Example: A mixture of chloroform and acetone

In case of solutions showing negative deviations, ΔmixH has a negative sign.

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2014-2015 (March) Foreign Set 2

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