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प्रश्न
Using sodium hydroxide solution, how will you distinguish:
Iron (II) chloride from iron (III) chloride
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उत्तर
Iron (II) chloride from iron (III) chloride
(i) \[\ce{FeCl2 + 2NaOH -> Fe(OH)2 + 2NaCI}\]
Fe(OH)2 precipitates are dirty green gelatinous in nature.
(ii) \[\ce{FeCl3 + 3NaOH -> Fe(OH)3 + 3NaCI}\]
Fe(OH)3 precipitates are reddish brown in colour.
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संबंधित प्रश्न
Name the kind of particles present in sodium hydroxide solution.
What do you observe when caustic soda solution is added to the following solution, first a little and then in excess:
Pb(NO3)2
Write balanced equation for this reaction.
Distinguish by adding:
(a) sodium hydroxide solution and
(b) Ammonium hydroxide solution to
(i) Calcium salt solution and lead salt solution
(ii) Lead salt solution and ferrous salt solution
(iii) copper salt solution and ferrous salt solution
(iv) Fe (II) salt solution and Fe (III) Salt solution
(v) Ferrous nitrate and lead nitrate
Using sodium hydroxide solution, how will you distinguish:
Lead hydroxide from magnesium hydroxide.
Write equation for the reaction that will take place when copper sulphate solution is added to sodium hydroxide solution.
Choose the correct answer from the options given below :
Hydroxide of this metal is soluble is sodium hydroxide solution
Using Sodium hydroxide solution, how would you distinguish: Zinc nitrate solution from calcium nitrate solution.
Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).
| Aqueous salt solution | Colour of precipitate when NaOH is added in a small quantity | Nature of precipitate (soluble or insoluble) when NaOH is added in excess |
| Copper (II) sulphate | (i) | (vi) |
| Zinc nitrate | (ii) | (vii) |
| Lead nitrate | (iii) | (viii) |
| Calcium chloride | (iv) | (ix) |
| Iron (III) Sulphate | (v) | (x) |
Sodium hydroxide solution is added to the solutions containing the ions mentioned in List X. List Y gives the details of the precipitate. Match the ions with their coloured precipitates.
| List X | List Y |
| (i) Pb2+ | (A) Reddish Brown |
| (ii) Fe2+ | (B) White insoluble inexcess |
| (iii) Zn2+ | (C) Dirty green |
| (iv) Fe3+ | (D) White soluble in excess |
| (v) Cu2+ | (E) White soluble in excess |
| (vi) Ca2+ | (F) Blue |
Name the metal hydroxides which are insoluble in caustic soda solution.
