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प्रश्न
What do you observe when caustic soda solution is added to the following solution, first a little and then in excess:
Pb(NO3)2
Write balanced equation for this reaction.
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उत्तर
\[\ce{Pb(NO3)2 + 2NaOH -> \underset{\text{White ppt.}}{Pb(OH)2↓} + \underset{\text{colourless}}{2NaNO3}}\]
In excess of alkali, white precipitate of Pb(OH)2 becomes soluble :
\[\ce{Pb(OH)2 + 2NaOH(excess) ->\underset{\text{Sodium Plumbate (colourless)}}{Na2PbO2 + 2H2O}}\]
संबंधित प्रश्न
Distinguish by adding:
(a) sodium hydroxide solution and
(b) Ammonium hydroxide solution to
(i) Calcium salt solution and lead salt solution
(ii) Lead salt solution and ferrous salt solution
(iii) copper salt solution and ferrous salt solution
(iv) Fe (II) salt solution and Fe (III) Salt solution
(v) Ferrous nitrate and lead nitrate
Using sodium hydroxide solution, how will you distinguish:
Lead hydroxide from magnesium hydroxide.
Three test tubes contain calcium nitrate solution, zinc nitrate solution and lead nitrate solution.Describe the effect of Adding sodium hydroxide solution to each portion in turn till it is in excess.
Write the observation, and balanced equation for the following reaction:
Sodium hydroxide is added dropwise to a solution of zinc sulphate, till it is in excess.
A white solid A when heated with sodium hydroxide solution, gives a pungent gas B, which turns red litmus blue. The solid, when dissolved in dilute nitric acid and treated with silver nitrate gives a white precipitate of C which is soluble in an ammonia solution.
Sodium hydroxide solution is added to the solutions containing the ions mentioned in List X. List Y gives the details of the precipitate. Match the ions with their coloured precipitates.
| List X | List Y |
| (i) Pb2+ | (A) Reddish Brown |
| (ii) Fe2+ | (B) White insoluble inexcess |
| (iii) Zn2+ | (C) Dirty green |
| (iv) Fe3+ | (D) White soluble in excess |
| (v) Cu2+ | (E) White soluble in excess |
| (vi) Ca2+ | (F) Blue |
State your observation of the following case :
When excess sodium hydroxide is added to calcium nitrate solution
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to lead nitrate solution and zinc nitrate solution.
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to copper salt solution and ferrous salt solution.
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to Fe(II) salt solution and Fe(III) salt solution.
