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प्रश्न
What do you observe when caustic soda solution is added to the following solution, first a little and then in excess:
Pb(NO3)2
Write balanced equation for this reaction.
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उत्तर
\[\ce{Pb(NO3)2 + 2NaOH -> \underset{\text{White ppt.}}{Pb(OH)2↓} + \underset{\text{colourless}}{2NaNO3}}\]
In excess of alkali, white precipitate of Pb(OH)2 becomes soluble :
\[\ce{Pb(OH)2 + 2NaOH(excess) ->\underset{\text{Sodium Plumbate (colourless)}}{Na2PbO2 + 2H2O}}\]
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संबंधित प्रश्न
Identify the substance underlined, in the following case:
Cation that does not form a precipitate with ammonium hydroxide but forms one with sodium hydroxide.
State one relevant observation for given reactions:
Action of Sodium hydroxide solution on ferrous sulfate solution.
What do you observe when ammonium salt is heated with caustic soda solution?
Using sodium hydroxide solution, how will you distinguish:
Iron (II) chloride from iron (III) chloride
Write the observation, and balanced equation for the following reaction:
Sodium hydroxide is added dropwise to a solution of zinc sulphate, till it is in excess.
Using Sodium hydroxide solution, how would you distinguish: Iron(II) chloride from Iron (III) chloride
Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).
| Aqueous salt solution | Colour of precipitate when NaOH is added in a small quantity | Nature of precipitate (soluble or insoluble) when NaOH is added in excess |
| Copper (II) sulphate | (i) | (vi) |
| Zinc nitrate | (ii) | (vii) |
| Lead nitrate | (iii) | (viii) |
| Calcium chloride | (iv) | (ix) |
| Iron (III) Sulphate | (v) | (x) |
Identify the cation in the following case:
Sodium hydroxide solution when added to Solution C gives a white precipitate which is insoluble in excess of sodium hydroxide solution.
Aqueous lead (II) nitrate can be distinguished from aqueous zinc nitrate by adding any of the following solutions in excess, except:
Write the word equation when ammonium salt is heated with caustic soda solution.
