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प्रश्न
A white solid A when heated with sodium hydroxide solution, gives a pungent gas B, which turns red litmus blue. The solid, when dissolved in dilute nitric acid and treated with silver nitrate gives a white precipitate of C which is soluble in an ammonia solution.
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उत्तर
C is silver chloride which is soluble in ammonia.
Pungent smelling gas B is ammonia.
White solid A is ammonium chloride.
\[\ce{NH4Cl(s) ->[NaOH] NH3(g) + H2O + NaCl}\]
\[\ce{NH3(g) ->[Red litmus] blue litmus}\]
\[\ce{\underset{\text{A}}{NH4Cl(s)} ->[AgNO3][HNO3] \underset{\text{C}}{AgCl(s)}}\]
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संबंधित प्रश्न
Identify the substance underlined, in the following case:
Cation that does not form a precipitate with ammonium hydroxide but forms one with sodium hydroxide.
Name a yellow monoxide that dissolves in hot and concentrated caustic alkali.
Three test tubes contain calcium nitrate solution, zinc nitrate solution and lead nitrate solution.Describe the effect of Adding sodium hydroxide solution to each portion in turn till it is in excess.
Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).
| Aqueous salt solution | Colour of precipitate when NaOH is added in a small quantity | Nature of precipitate (soluble or insoluble) when NaOH is added in excess |
| Copper (II) sulphate | (i) | (vi) |
| Zinc nitrate | (ii) | (vii) |
| Lead nitrate | (iii) | (viii) |
| Calcium chloride | (iv) | (ix) |
| Iron (III) Sulphate | (v) | (x) |
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to calcium salt solution and lead salt solution.
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to copper salt solution and ferrous salt solution.
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to Fe(II) salt solution and Fe(III) salt solution.
Identify the cation in the following case:
Sodium hydroxide solution when added to Solution C gives a white precipitate which is insoluble in excess of sodium hydroxide solution.
Aqueous lead (II) nitrate can be distinguished from aqueous zinc nitrate by adding any of the following solutions in excess, except:
A student was asked to perform an experiment in the laboratory based on the instructions given:
Observe the picture given below and state one observation for the experiment you would notice on mixing the given solution.
