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प्रश्न
A white solid A when heated with sodium hydroxide solution, gives a pungent gas B, which turns red litmus blue. The solid, when dissolved in dilute nitric acid and treated with silver nitrate gives a white precipitate of C which is soluble in an ammonia solution.
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उत्तर
C is silver chloride which is soluble in ammonia.
Pungent smelling gas B is ammonia.
White solid A is ammonium chloride.
\[\ce{NH4Cl(s) ->[NaOH] NH3(g) + H2O + NaCl}\]
\[\ce{NH3(g) ->[Red litmus] blue litmus}\]
\[\ce{\underset{\text{A}}{NH4Cl(s)} ->[AgNO3][HNO3] \underset{\text{C}}{AgCl(s)}}\]
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संबंधित प्रश्न
State one relevant observation for given reactions:
Action of Sodium hydroxide solution on ferrous sulfate solution.
Identify the cations in the following case:
NaOH solution, when added to the Solution (A), gives a reddish brown precipitate
What do you observe when caustic soda solution is added to the following solution, first a little and then in excess:
ZnSO4
Write a balanced equation for this reaction.
Using sodium hydroxide solution, how will you distinguish: Zinc nitrate solution from calcium nitrate solution
Write the observation, and balanced equation for the following reaction:
Sodium hydroxide is added dropwise to a solution of zinc sulphate, till it is in excess.
Using Sodium hydroxide solution, how would you distinguish: Iron(II) chloride from Iron (III) chloride
Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).
| Aqueous salt solution | Colour of precipitate when NaOH is added in a small quantity | Nature of precipitate (soluble or insoluble) when NaOH is added in excess |
| Copper (II) sulphate | (i) | (vi) |
| Zinc nitrate | (ii) | (vii) |
| Lead nitrate | (iii) | (viii) |
| Calcium chloride | (iv) | (ix) |
| Iron (III) Sulphate | (v) | (x) |
Sodium hydroxide solution is added to the solutions containing the ions mentioned in List X. List Y gives the details of the precipitate. Match the ions with their coloured precipitates.
| List X | List Y |
| (i) Pb2+ | (A) Reddish Brown |
| (ii) Fe2+ | (B) White insoluble inexcess |
| (iii) Zn2+ | (C) Dirty green |
| (iv) Fe3+ | (D) White soluble in excess |
| (v) Cu2+ | (E) White soluble in excess |
| (vi) Ca2+ | (F) Blue |
State your observation of the following case :
When excess sodium hydroxide is added to calcium nitrate solution
Write the word equation when ammonium salt is heated with caustic soda solution.
