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प्रश्न
Using sodium hydroxide solution, how will you distinguish:
Iron (II) chloride from iron (III) chloride
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उत्तर
Iron (II) chloride from iron (III) chloride
(i) \[\ce{FeCl2 + 2NaOH -> Fe(OH)2 + 2NaCI}\]
Fe(OH)2 precipitates are dirty green gelatinous in nature.
(ii) \[\ce{FeCl3 + 3NaOH -> Fe(OH)3 + 3NaCI}\]
Fe(OH)3 precipitates are reddish brown in colour.
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संबंधित प्रश्न
Name a yellow monoxide that dissolves in hot and concentrated caustic alkali.
Distinguish by adding:
(a) sodium hydroxide solution and
(b) Ammonium hydroxide solution to
(i) Calcium salt solution and lead salt solution
(ii) Lead salt solution and ferrous salt solution
(iii) copper salt solution and ferrous salt solution
(iv) Fe (II) salt solution and Fe (III) Salt solution
(v) Ferrous nitrate and lead nitrate
Using sodium hydroxide solution, how will you distinguish: Zinc nitrate solution from calcium nitrate solution
Write equation for the reaction that will take place when copper sulphate solution is added to sodium hydroxide solution.
Identify the substance Q based on the information given below:
The white crystalline solid Q is soluble in water. It liberates a pungent smelling gas when heated with sodium hydroxide solution.
Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).
| Aqueous salt solution | Colour of precipitate when NaOH is added in a small quantity | Nature of precipitate (soluble or insoluble) when NaOH is added in excess |
| Copper (II) sulphate | (i) | (vi) |
| Zinc nitrate | (ii) | (vii) |
| Lead nitrate | (iii) | (viii) |
| Calcium chloride | (iv) | (ix) |
| Iron (III) Sulphate | (v) | (x) |
State your observation of the following case :
When excess sodium hydroxide is added to calcium nitrate solution
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to calcium salt solution and lead salt solution.
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to ferrous nitrate and lead nitrate.
Identify the cation in the following case:
Sodium hydroxide solution when added to Solution C gives a white precipitate which is insoluble in excess of sodium hydroxide solution.
